New ionic polymers by cellulose functionalization
1998; Wiley; Volume: 199; Issue: 11 Linguagem: Inglês
10.1002/macp.1998.021991101
ISSN1521-3935
Autores Tópico(s)Ionic liquids properties and applications
ResumoMacromolecular Chemistry and PhysicsVolume 199, Issue 11 p. 2341-2364 Feature Article New ionic polymers by cellulose functionalization Thomas Heinze, Thomas Heinze Friedrich Schiller University of Jena, Humboldtstrasse 10, D-07743 Jena, GermanySearch for more papers by this author Thomas Heinze, Thomas Heinze Friedrich Schiller University of Jena, Humboldtstrasse 10, D-07743 Jena, GermanySearch for more papers by this author First published: 16 December 1998 https://doi.org/10.1002/(SICI)1521-3935(19981101)199:11 3.0.CO;2-JCitations: 117AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract The unique structure and reactivity of cellulose opens up various possibilities for the design of advanced materials based on this biomacromolecule. In the present feature the state of the art of selected cellulose functionalization reactions is discussed adequately considering own research results. In particular, new synthesis paths to ionic cellulosics, both with controlled functionalization patterns and unconventional combinations of different functional groups (hydrophilic-lipophilic), as well as new synthesis concepts are presented. An important approach to new cellulosics is the reaction via an induced phase separation with solid alkali hydroxide particles. Starting from solutions of cellulose in N,N-dimethylacetamide/LiCl or from organo-soluble cellulose derivatives of different hydrolytic stability dissolved in dimethyl sulfoxide, subsequent etherification and esterification yield cellulose products of unconventional functionalization patterns and properties. Not only reactions directed towards the hydroxyl groups—the primary reactive sites—is given attention but also nucleophilic displacement reactions at the carbon atoms appear as synthesis tool to new polysaccharide materials. References 1 H. Dautzenberg, W. Jaeger, J. Kötz, B. Philipp, Ch. Seidel, D. Stscherbina, Polyelectrolytes, Formation, Characterization and Application, Hanser Publ., München, Wien, New York 1994 Google Scholar 2 G. Ebert, Biopolymere, Teubner, Stuttgart 1993 Google Scholar 3 O. Smidsrod, K. J. Draget, Carbohydr. Eur. 14, 6 (1996) Google Scholar 4 I. C. M. Dea, Pure Appl. Chem. 61, 1315 (1989) 10.1351/pac198961071315 CASWeb of Science®Google Scholar 5 E. 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