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Rh I ‐Catalyzed CC Bond Activation: Seven‐Membered Ring Synthesis by a [6+1] Carbonylative Ring‐Expansion Reaction of Allenylcyclobutanes

2006; Wiley; Volume: 118; Issue: 24 Linguagem: Inglês

10.1002/ange.200600806

1521-3757

Paul A. Wender, Nicole M. Deschamps, Robert Sun,

Catalytic Cross-Coupling Reactions

Angewandte ChemieVolume 118, Issue 24 p. 4061-4064 Zuschrift RhI-Catalyzed CC Bond Activation: Seven-Membered Ring Synthesis by a [6+1] Carbonylative Ring-Expansion Reaction of Allenylcyclobutanes† Paul A. Wender Prof., Paul A. Wender Prof. wenderp@stanford.edu Department of Chemistry, Department of Molecular Pharmacology, Stanford University, Stanford, CA 94305-5080, USA, Fax: (+1) 650-725-0259Search for more papers by this authorNicole M. Deschamps, Nicole M. Deschamps Department of Chemistry, Department of Molecular Pharmacology, Stanford University, Stanford, CA 94305-5080, USA, Fax: (+1) 650-725-0259Search for more papers by this authorRobert Sun, Robert Sun Department of Chemistry, Department of Molecular Pharmacology, Stanford University, Stanford, CA 94305-5080, USA, Fax: (+1) 650-725-0259Search for more papers by this author Paul A. Wender Prof., Paul A. Wender Prof. wenderp@stanford.edu Department of Chemistry, Department of Molecular Pharmacology, Stanford University, Stanford, CA 94305-5080, USA, Fax: (+1) 650-725-0259Search for more papers by this authorNicole M. Deschamps, Nicole M. Deschamps Department of Chemistry, Department of Molecular Pharmacology, Stanford University, Stanford, CA 94305-5080, USA, Fax: (+1) 650-725-0259Search for more papers by this authorRobert Sun, Robert Sun Department of Chemistry, Department of Molecular Pharmacology, Stanford University, Stanford, CA 94305-5080, USA, Fax: (+1) 650-725-0259Search for more papers by this author First published: 01 June 2006 https://doi.org/10.1002/ange.200600806Citations: 27 † This research was supported by the National Science Foundation (CHE-040638). Fellowship support from Eli Lilly and Company (R.S. and N.M.D.) is gratefully acknowledged. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Expandieren: Eine Rhodium(I)-katalysierte C-C-Aktivierung von Allenylcyclobutanen liefert Metallacyclen-Intermediate, die mit CO abgefangen werden. Funktionalisierte mono- wie bicyclische Cycloheptenone werden mit dieser neuen carbonylierenden [6+1]-Cycloaddition höherer Ordnung in guten bis ausgezeichneten Ausbeuten erhalten. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2006/z600806_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume118, Issue24June 12, 2006Pages 4061-4064 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation