Iron‐Catalyzed Enantioselective Hydrosilylation of Ketones
2008; Wiley; Volume: 120; Issue: 13 Linguagem: Inglês
10.1002/ange.200705624
ISSN1521-3757
AutoresNadim S. Shaikh, Stephan Enthaler, Kathrin Junge, Matthias Beller,
Tópico(s)Chemical Synthesis and Analysis
ResumoAngewandte ChemieVolume 120, Issue 13 p. 2531-2535 Zuschrift Iron-Catalyzed Enantioselective Hydrosilylation of Ketones† Nadim S. Shaikh Dr., Nadim S. Shaikh Dr. Leibniz-Institut für Katalyse e.V. Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany, Fax: (+49) 381-1281-5000Search for more papers by this authorStephan Enthaler Dr., Stephan Enthaler Dr. Leibniz-Institut für Katalyse e.V. Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany, Fax: (+49) 381-1281-5000Search for more papers by this authorKathrin Junge Dr., Kathrin Junge Dr. Leibniz-Institut für Katalyse e.V. Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany, Fax: (+49) 381-1281-5000Search for more papers by this authorMatthias Beller Prof. Dr., Matthias Beller Prof. Dr. matthias.beller@catalysis.de Leibniz-Institut für Katalyse e.V. Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany, Fax: (+49) 381-1281-5000Search for more papers by this author Nadim S. Shaikh Dr., Nadim S. Shaikh Dr. Leibniz-Institut für Katalyse e.V. Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany, Fax: (+49) 381-1281-5000Search for more papers by this authorStephan Enthaler Dr., Stephan Enthaler Dr. Leibniz-Institut für Katalyse e.V. Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany, Fax: (+49) 381-1281-5000Search for more papers by this authorKathrin Junge Dr., Kathrin Junge Dr. Leibniz-Institut für Katalyse e.V. Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany, Fax: (+49) 381-1281-5000Search for more papers by this authorMatthias Beller Prof. Dr., Matthias Beller Prof. Dr. matthias.beller@catalysis.de Leibniz-Institut für Katalyse e.V. Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany, Fax: (+49) 381-1281-5000Search for more papers by this author First published: 10 March 2008 https://doi.org/10.1002/ange.200705624Citations: 105 † N.S.S. thanks the Alexander von Humboldt Foundation (Bonn,Germany) for a postdoctoral research fellowship. We gratefully acknowledge Evonik (formerly Degussa) for the precious gift of ligands L5–L12. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Mit einem Eisen-Katalysator: Die Hydrosilylierung prochiraler Ketone in Gegenwart von billigen und umweltverträglichen Eisenkatalysatoren und (S,S)-Me-Duphos (1,2-(Bis[(2S,5S)]-2,5-dimethylphospholano)benzol) überführt zahlreiche Arylketone mit bis zu 99 % Enantioselektivität und quantitativen Ausbeuten in die sekundären Alkohole (siehe Schema). Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2008/z705624_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume120, Issue13March 14, 2008Pages 2531-2535 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation
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