Selective Assembly and Disassembly of a Water‐Soluble Fe 10 L 15 Prism
2013; Wiley; Volume: 125; Issue: 18 Linguagem: Inglês
10.1002/ange.201209694
ISSN1521-3757
AutoresSalvatore Zarra, Jack K. Clegg, Jonathan R. Nitschke,
Tópico(s)Polyoxometalates: Synthesis and Applications
ResumoAngewandte ChemieVolume 125, Issue 18 p. 4937-4940 Zuschrift Selective Assembly and Disassembly of a Water-Soluble Fe10L15 Prism† Salvatore Zarra, Salvatore Zarra Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW (UK) http://www-jrn.ch.cam.ac.uk/Search for more papers by this authorDr. Jack K. Clegg, Dr. Jack K. Clegg Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW (UK) http://www-jrn.ch.cam.ac.uk/ Current address: School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane St Lucia, QLD 4072 (Australia)Search for more papers by this authorDr. Jonathan R. Nitschke, Corresponding Author Dr. Jonathan R. Nitschke [email protected] Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW (UK) http://www-jrn.ch.cam.ac.uk/Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW (UK) http://www-jrn.ch.cam.ac.uk/Search for more papers by this author Salvatore Zarra, Salvatore Zarra Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW (UK) http://www-jrn.ch.cam.ac.uk/Search for more papers by this authorDr. Jack K. Clegg, Dr. Jack K. Clegg Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW (UK) http://www-jrn.ch.cam.ac.uk/ Current address: School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane St Lucia, QLD 4072 (Australia)Search for more papers by this authorDr. Jonathan R. Nitschke, Corresponding Author Dr. Jonathan R. Nitschke [email protected] Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW (UK) http://www-jrn.ch.cam.ac.uk/Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW (UK) http://www-jrn.ch.cam.ac.uk/Search for more papers by this author First published: 26 February 2013 https://doi.org/10.1002/ange.201209694Citations: 25 † This work was supported by the EPSRC and the Marie Curie IIF Scheme of the 7th EU Framework Program. We thank the EPSRC Mass Spectrometry Service at Swansea for conducting ESI-MS experiments, the Diamond Light Source (UK) for synchrotron beam time on I19, the EPSRC National Crystallography Service for X-ray data collection, and Duncan Howe from the NMR service of the Department of Chemistry at the University of Cambridge. We thank Prof. Andrea Mazzanti for the helpful discussions concerning the conformational dynamics of the system. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Survival of the fittest: Die gleichen Bausteine führten unter verschiedenen Reaktionsbedingungen selektiv zu zwei wasserlöslichen metallorganischen Strukturen, einem Tetraeder und einem pentagonalen Prisma. Nach Zugabe von 4-Methoxyanilin zu einer Mischung der beiden Strukturen wurde das Prisma zu einem einkernigen Komplex abgebaut, und die stabilere Tetraederstruktur blieb erhalten. 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