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Chilled ammonia process for CO2 capture

2009; Elsevier BV; Volume: 1; Issue: 1 Linguagem: Inglês

10.1016/j.egypro.2009.01.137

1876-6102

Victor Darde, Kaj Thomsen, Willy J. M. van Well, Erling H. Stenby,

Membrane Separation and Gas Transport

The chilled ammonia process absorbs the CO2 at low temperature (2–10 ∘C). The heat of absorption of carbon dioxide by ammonia is significantly lower than for amines. In addition, degradation problems can be avoided and a high carbon dioxide capacity is achieved. Hence, this process shows good perspectives for decreasing the energy requirement. However, a scientific understanding of the processes is required. The properties of the NH3- CO2- H2O system were described using the Extended UNIQUAC electrolyte model developed by Thomsen and Rasmussen in a temperature range from 0 to 110 ∘C and pressure up to 100 bars [1]. The results show that solid phases consisting of ammonium carbonate and bicarbonate are formed in the absorber. The energy requirements in the absorber and in the desorber have been studied. The enthalpy calculations show that an energy requirement for the desorber lower than 2 GJ/ton CO2 can be reached.