Visual Chiral Recognition through Enantioselective Metallogel Collapsing: Synthesis, Characterization, and Application of Platinum–Steroid Low‐Molecular‐Mass Gelators
2011; Wiley; Volume: 123; Issue: 29 Linguagem: Inglês
10.1002/ange.201180620
ISSN1521-3757
AutoresTao Tu, Weiwei Fang, Xiaoling Bao, Xinbao Li, Karl Heinz Dötz,
Tópico(s)Polyoxometalates: Synthesis and Applications
ResumoAngewandte ChemieVolume 123, Issue 29 p. 6731-6735 Zuschrift Visual Chiral Recognition through Enantioselective Metallogel Collapsing: Synthesis, Characterization, and Application of Platinum–Steroid Low-Molecular-Mass Gelators† Dr. Tao Tu, Corresponding Author Dr. Tao Tu [email protected] Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry, Fudan University, 220 Handan Road, 200433, Shanghai (China), Fax: (+86) 21-65102412Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry, Fudan University, 220 Handan Road, 200433, Shanghai (China), Fax: (+86) 21-65102412Search for more papers by this authorWeiwei Fang, Weiwei Fang Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry, Fudan University, 220 Handan Road, 200433, Shanghai (China), Fax: (+86) 21-65102412Search for more papers by this authorXiaoling Bao, Xiaoling Bao Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry, Fudan University, 220 Handan Road, 200433, Shanghai (China), Fax: (+86) 21-65102412Search for more papers by this authorXinbao Li, Xinbao Li Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry, Fudan University, 220 Handan Road, 200433, Shanghai (China), Fax: (+86) 21-65102412Search for more papers by this authorProf. Karl Heinz Dötz, Prof. Karl Heinz Dötz Kekulé-Institute of Organic Chemistry and Biochemistry, University of Bonn (Germany)Search for more papers by this author Dr. Tao Tu, Corresponding Author Dr. Tao Tu [email protected] Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry, Fudan University, 220 Handan Road, 200433, Shanghai (China), Fax: (+86) 21-65102412Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry, Fudan University, 220 Handan Road, 200433, Shanghai (China), Fax: (+86) 21-65102412Search for more papers by this authorWeiwei Fang, Weiwei Fang Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry, Fudan University, 220 Handan Road, 200433, Shanghai (China), Fax: (+86) 21-65102412Search for more papers by this authorXiaoling Bao, Xiaoling Bao Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry, Fudan University, 220 Handan Road, 200433, Shanghai (China), Fax: (+86) 21-65102412Search for more papers by this authorXinbao Li, Xinbao Li Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry, Fudan University, 220 Handan Road, 200433, Shanghai (China), Fax: (+86) 21-65102412Search for more papers by this authorProf. Karl Heinz Dötz, Prof. Karl Heinz Dötz Kekulé-Institute of Organic Chemistry and Biochemistry, University of Bonn (Germany)Search for more papers by this author First published: 06 July 2011 https://doi.org/10.1002/ange.201180620Citations: 61 † Financial support from the National Natural Science Foundation of China (No. 20902011), the Shanghai Municipal Science and Technology Commission (Qimingxing Program No. 10A1400500), the Shanghai Leading Academic Discipline Project (B108), and Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials (2010MCIMKF04), Department of Chemistry, Fudan University is gratefully acknowledged. We thank Prof. Tao Yi and Prof. Qi-Lin Zhou for technical support. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Sehen um zu glauben: Die optische chirale Erkennung von (R)- und (S)-Binap gelang mithilfe des enantioselektiven Kollabierens von Metallogelen, die mit neuartigen Gelatoren aus Platin und Pinzettenliganden mit aromatischem, Linker- und Steroidteil hergestellt wurden. Van-der-Waals-Wechselwirkungen, π-Stapelung und Metall-Metall-Bindung führen zur Aggregation und chiralen Erkennung. Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_201180620_sm_miscellaneous_information.pdf11.6 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 1a Chiral Recognition in the Gas Phase (Ed.: ), Woodhead, Cambridge, UK, 2010; Google Scholar 1b Chirality in Drug Research (Eds.: ), Wiley-VCH, Weinheim, 2006; Google Scholar 1c Chirality in Natural and Applied Science (Eds.: ), Blackwell, Oxford, UK, 2002. Google Scholar 2 2aSelected recent reviews of chiral recognition: G. A. Hembury, V. V. Borovkov, Y. Inoue, Chem. 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