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Beyond the Icosahedron: The First 13‐Vertex Carborane

2003; Wiley; Volume: 115; Issue: 2 Linguagem: Inglês

10.1002/ange.200390053

1521-3757

Anthony J. Burke, David Ellis, B.T. Giles, B.E. Hodson, Stuart A. Macgregor, Georgina M. Rosair, Alan J. Welch,

Organoboron and organosilicon chemistry

Angewandte ChemieVolume 115, Issue 2 p. 235-238 Zuschrift Beyond the Icosahedron: The First 13-Vertex Carborane† Anthony Burke, Anthony Burke Department of Chemistry Heriot-Watt University Edinburgh EH14 4AS, UK, Fax: (+44) 131-451-3180Search for more papers by this authorDavid Ellis Dr., David Ellis Dr. Department of Chemistry Heriot-Watt University Edinburgh EH14 4AS, UK, Fax: (+44) 131-451-3180Search for more papers by this authorBarry T. Giles, Barry T. Giles Department of Chemistry Heriot-Watt University Edinburgh EH14 4AS, UK, Fax: (+44) 131-451-3180Search for more papers by this authorBruce E. Hodson Dr., Bruce E. Hodson Dr. Department of Chemistry Heriot-Watt University Edinburgh EH14 4AS, UK, Fax: (+44) 131-451-3180Search for more papers by this authorStuart A. Macgregor Dr., Stuart A. Macgregor Dr. Department of Chemistry Heriot-Watt University Edinburgh EH14 4AS, UK, Fax: (+44) 131-451-3180Search for more papers by this authorGeorgina M. Rosair Dr., Georgina M. Rosair Dr. Department of Chemistry Heriot-Watt University Edinburgh EH14 4AS, UK, Fax: (+44) 131-451-3180Search for more papers by this authorAlan J. Welch Prof., Alan J. Welch Prof. a.j.welch@hw.ac.uk Department of Chemistry Heriot-Watt University Edinburgh EH14 4AS, UK, Fax: (+44) 131-451-3180Search for more papers by this author Anthony Burke, Anthony Burke Department of Chemistry Heriot-Watt University Edinburgh EH14 4AS, UK, Fax: (+44) 131-451-3180Search for more papers by this authorDavid Ellis Dr., David Ellis Dr. Department of Chemistry Heriot-Watt University Edinburgh EH14 4AS, UK, Fax: (+44) 131-451-3180Search for more papers by this authorBarry T. Giles, Barry T. Giles Department of Chemistry Heriot-Watt University Edinburgh EH14 4AS, UK, Fax: (+44) 131-451-3180Search for more papers by this authorBruce E. Hodson Dr., Bruce E. Hodson Dr. Department of Chemistry Heriot-Watt University Edinburgh EH14 4AS, UK, Fax: (+44) 131-451-3180Search for more papers by this authorStuart A. Macgregor Dr., Stuart A. Macgregor Dr. Department of Chemistry Heriot-Watt University Edinburgh EH14 4AS, UK, Fax: (+44) 131-451-3180Search for more papers by this authorGeorgina M. Rosair Dr., Georgina M. Rosair Dr. Department of Chemistry Heriot-Watt University Edinburgh EH14 4AS, UK, Fax: (+44) 131-451-3180Search for more papers by this authorAlan J. Welch Prof., Alan J. Welch Prof. a.j.welch@hw.ac.uk Department of Chemistry Heriot-Watt University Edinburgh EH14 4AS, UK, Fax: (+44) 131-451-3180Search for more papers by this author First published: January 13, 2003 https://doi.org/10.1002/ange.200390053Citations: 32 † We thank D. Ferrer, M. A. Laguna, and F. Schmidt for preliminary experiments. We acknowledge the EPSRC and the Leverhulme Trust for support of this work. We also thank A. S. F. Boyd for NMR spectra, R. Ferguson for mass spectra and G. Evans for microanalyses. A.J.W is the recipient of a Royal Society Leverhulme Trust Senior Research Fellowship. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Betrifft die 13. Ecke: Das erste 13-eckige Carboran (siehe Bild; B: braun, C: grau, H: weiß) wurde mithilfe eines Verfahrens hergestellt, das prinzipiell wiederholt angewendet werden kann, sodass künftig auch 14-, 15-, 16- und mehr-eckige Carborane zugänglich sind. Das 13-eckige Molekül hat eine henikosaedrische und keine dokosaedrische Geometrie wie ursprünglich angenommen. Beide Konfigurationen sind gemäß DFT-Rechnungen energetisch ähnlich. Citing Literature Volume115, Issue2January 13, 2003Pages 235-238 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation