Stereocomplex of Poly(propylene carbonate): Synthesis of Stereogradient Poly(propylene carbonate) by Regio‐ and Enantioselective Copolymerization of Propylene Oxide with Carbon Dioxide
2011; Wiley; Volume: 123; Issue: 21 Linguagem: Inglês
10.1002/ange.201007958
ISSN1521-3757
AutoresKoji Nakano, Shinichi Hashimoto, Mitsuru Nakamura, Toshihiro Kamada, Kyoko Nozaki,
Tópico(s)Chemistry and Chemical Engineering
ResumoAngewandte ChemieVolume 123, Issue 21 p. 4970-4973 Zuschrift Stereocomplex of Poly(propylene carbonate): Synthesis of Stereogradient Poly(propylene carbonate) by Regio- and Enantioselective Copolymerization of Propylene Oxide with Carbon Dioxide† Dr. Koji Nakano, Dr. Koji Nakano Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656 Tokyo (Japan), Fax: (+81) 3-5841-7263Search for more papers by this authorShinichi Hashimoto, Shinichi Hashimoto Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656 Tokyo (Japan), Fax: (+81) 3-5841-7263Search for more papers by this authorMitsuru Nakamura, Mitsuru Nakamura Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656 Tokyo (Japan), Fax: (+81) 3-5841-7263Search for more papers by this authorToshihiro Kamada, Toshihiro Kamada Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656 Tokyo (Japan), Fax: (+81) 3-5841-7263Search for more papers by this authorProf. Kyoko Nozaki, Corresponding Author Prof. Kyoko Nozaki [email protected] Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656 Tokyo (Japan), Fax: (+81) 3-5841-7263Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656 Tokyo (Japan), Fax: (+81) 3-5841-7263Search for more papers by this author Dr. Koji Nakano, Dr. Koji Nakano Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656 Tokyo (Japan), Fax: (+81) 3-5841-7263Search for more papers by this authorShinichi Hashimoto, Shinichi Hashimoto Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656 Tokyo (Japan), Fax: (+81) 3-5841-7263Search for more papers by this authorMitsuru Nakamura, Mitsuru Nakamura Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656 Tokyo (Japan), Fax: (+81) 3-5841-7263Search for more papers by this authorToshihiro Kamada, Toshihiro Kamada Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656 Tokyo (Japan), Fax: (+81) 3-5841-7263Search for more papers by this authorProf. Kyoko Nozaki, Corresponding Author Prof. Kyoko Nozaki [email protected] Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656 Tokyo (Japan), Fax: (+81) 3-5841-7263Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656 Tokyo (Japan), Fax: (+81) 3-5841-7263Search for more papers by this author First published: 04 March 2011 https://doi.org/10.1002/ange.201007958Citations: 33 † We are grateful to Prof. Yoshiaki Nishibayashi and Prof. Yoshihiro Miyake for carrying out HRMS analysis. This work was supported by a Grant-in-Aid for Scientific Research (A; 21245023), Innovative Areas "Molecular Activation Directed toward Straightforward Synthesis" from the Ministry of Education, Culture, Sports, Science and Technology (Japan), and a Grant for Practical Application of University R&D Results under the Matching Fund Method from the New Energy and Industrial Technology Development Organization (NEDO). Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Cobalt(III)-Salen-Komplexe mit Ammoniumseitenkette(n) katalysieren die Titelreaktion. Auf diesem Weg erhaltenes Stereogradient- und Stereoblock-Polypropylencarbonat (PPC) verfügt über höhere Zersetzungstemperaturen als typische PPCs. Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_201007958_sm_miscellaneous_information.pdf617.3 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1a G. Natta, P. Pino, P. Corradini, F. Danusso, E. Mantica, G. Mazzanti, G. 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