Artigo Revisado por pares

Formal Synthesis of Leucascandrolide A

2003; Wiley; Volume: 42; Issue: 33 Linguagem: Inglês

10.1002/anie.200351817

ISSN

1521-3773

Autores

David R. Williams, Scott Plummer, Samarjit Patnaik,

Tópico(s)

Traditional and Medicinal Uses of Annonaceae

Resumo

Asymmetric allylation reactions of stannane-derived allyl diazaborolanes, and the use of the Terashima reagent for the highly selective asymmetric hydride reduction of a β-alkoxy ketone are key features of a highly convergent, stereocontrolled formal synthesis of leucascandrolide A (see picture).

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