Formal Synthesis of Leucascandrolide A
2003; Wiley; Volume: 42; Issue: 33 Linguagem: Inglês
10.1002/anie.200351817
ISSN1521-3773
AutoresDavid R. Williams, Scott Plummer, Samarjit Patnaik,
Tópico(s)Traditional and Medicinal Uses of Annonaceae
ResumoAsymmetric allylation reactions of stannane-derived allyl diazaborolanes, and the use of the Terashima reagent for the highly selective asymmetric hydride reduction of a β-alkoxy ketone are key features of a highly convergent, stereocontrolled formal synthesis of leucascandrolide A (see picture).
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