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Asymmetric Epoxidation of Conjugated Olefins with Dioxygen

2012; Wiley; Volume: 124; Issue: 33 Linguagem: Inglês

10.1002/ange.201201848

1521-3757

Shota Koya, Yota Nishioka, Hirotaka Mizoguchi, Tatsuya Uchida, Tsutomu Katsuki,

Metal complexes synthesis and properties

Angewandte ChemieVolume 124, Issue 33 p. 8368-8371 Zuschrift Asymmetric Epoxidation of Conjugated Olefins with Dioxygen† Shota Koya, Shota Koya Department of Chemistry, Faculty of Science, Graduate School, and International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan) http://www.scc.kyushu-u.ac.jp/Yuhan/Search for more papers by this authorYota Nishioka, Yota Nishioka Department of Chemistry, Faculty of Science, Graduate School, and International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan) http://www.scc.kyushu-u.ac.jp/Yuhan/Search for more papers by this authorHirotaka Mizoguchi, Hirotaka Mizoguchi Department of Chemistry, Faculty of Science, Graduate School, and International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan) http://www.scc.kyushu-u.ac.jp/Yuhan/Search for more papers by this authorDr. Tatsuya Uchida, Dr. Tatsuya Uchida Department of Chemistry, Faculty of Science, Graduate School, and International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan) http://www.scc.kyushu-u.ac.jp/Yuhan/Search for more papers by this authorProf. Tsutomu Katsuki, Corresponding Author Prof. Tsutomu Katsuki katsucc@chem.kyushu-univ.jp Department of Chemistry, Faculty of Science, Graduate School, and International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan) http://www.scc.kyushu-u.ac.jp/Yuhan/Department of Chemistry, Faculty of Science, Graduate School, and International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan) http://www.scc.kyushu-u.ac.jp/Yuhan/Search for more papers by this author Shota Koya, Shota Koya Department of Chemistry, Faculty of Science, Graduate School, and International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan) http://www.scc.kyushu-u.ac.jp/Yuhan/Search for more papers by this authorYota Nishioka, Yota Nishioka Department of Chemistry, Faculty of Science, Graduate School, and International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan) http://www.scc.kyushu-u.ac.jp/Yuhan/Search for more papers by this authorHirotaka Mizoguchi, Hirotaka Mizoguchi Department of Chemistry, Faculty of Science, Graduate School, and International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan) http://www.scc.kyushu-u.ac.jp/Yuhan/Search for more papers by this authorDr. Tatsuya Uchida, Dr. Tatsuya Uchida Department of Chemistry, Faculty of Science, Graduate School, and International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan) http://www.scc.kyushu-u.ac.jp/Yuhan/Search for more papers by this authorProf. Tsutomu Katsuki, Corresponding Author Prof. Tsutomu Katsuki katsucc@chem.kyushu-univ.jp Department of Chemistry, Faculty of Science, Graduate School, and International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan) http://www.scc.kyushu-u.ac.jp/Yuhan/Department of Chemistry, Faculty of Science, Graduate School, and International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan) http://www.scc.kyushu-u.ac.jp/Yuhan/Search for more papers by this author First published: 18 July 2012 https://doi.org/10.1002/ange.201201848Citations: 14 † Financial support from Nissan Chemical Industries, Ltd. and the World Premier International Research Center Initiative (WPI), the Global COE Program, “Science for Future Molecular Systems” and Grants-in-Aid for Scientific Research No. 23245009 from MEXT (Japan) is gratefully acknowledged. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Komplexe Sauerstoffquelle: Die asymmetrische Epoxidierung konjugierter Olefine mit dem Rutheniumkomplex 1 als Katalysator und Luft als Oxidationsmittel liefert bei Raumtemperatur die Epoxide mit bis zu 95 % ee. Säureempfindliche Produkte waren durch Reaktionen bei 0 °C unter Sauerstoff zugänglich. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_201201848_sm_miscellaneous_information.pdf2.4 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume124, Issue33August 13, 2012Pages 8368-8371 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation