Comparison of the Reactivity of Nonheme Iron(IV)–Oxo versus Iron(IV)–Imido Complexes: Which is the Better Oxidant?
2013; Wiley; Volume: 125; Issue: 47 Linguagem: Inglês
10.1002/ange.201305370
ISSN1521-3757
AutoresAnil Kumar Vardhaman, Prasenjit Barman, Suresh Kumar, Chivukula V. Sastri, Devesh Kumar, Sam P. de Visser,
Tópico(s)Magnetism in coordination complexes
ResumoAngewandte ChemieVolume 125, Issue 47 p. 12514-12518 Zuschrift Comparison of the Reactivity of Nonheme Iron(IV)–Oxo versus Iron(IV)–Imido Complexes: Which is the Better Oxidant?† Anil Kumar Vardhaman, Anil Kumar Vardhaman Department of Chemistry, Indian Institute of Technology Guwahati, Assam, 781039 (India)Search for more papers by this authorPrasenjit Barman, Prasenjit Barman Department of Chemistry, Indian Institute of Technology Guwahati, Assam, 781039 (India)Search for more papers by this authorSuresh Kumar, Suresh Kumar Department of Applied Physics, Babasaheb Bhimrao Ambedkar University, School for Physical Sciences, Vidya Vihar, Rae Bareilly Road, Lucknow (UP), 226025 (India)Search for more papers by this authorDr. Chivukula V. Sastri, Corresponding Author Dr. Chivukula V. Sastri sastricv@iitg.ernet.in Department of Chemistry, Indian Institute of Technology Guwahati, Assam, 781039 (India) Chivukula V. Sastri, Department of Chemistry, Indian Institute of Technology Guwahati, Assam, 781039 (India) Devesh Kumar, Department of Applied Physics, Babasaheb Bhimrao Ambedkar University, School for Physical Sciences, Vidya Vihar, Rae Bareilly Road, Lucknow (UP), 226025 (India) Sam P. de Visser, Manchester Institute of Biotechnology and School of Chemical Engineering and Analytical Science, The University of Manchester, 131 Princess Street, Manchester M1 7DN (United Kingdom)Search for more papers by this authorDr. Devesh Kumar, Corresponding Author Dr. Devesh Kumar dkclcre@yahoo.com Department of Applied Physics, Babasaheb Bhimrao Ambedkar University, School for Physical Sciences, Vidya Vihar, Rae Bareilly Road, Lucknow (UP), 226025 (India) Chivukula V. Sastri, Department of Chemistry, Indian Institute of Technology Guwahati, Assam, 781039 (India) Devesh Kumar, Department of Applied Physics, Babasaheb Bhimrao Ambedkar University, School for Physical Sciences, Vidya Vihar, Rae Bareilly Road, Lucknow (UP), 226025 (India) Sam P. de Visser, Manchester Institute of Biotechnology and School of Chemical Engineering and Analytical Science, The University of Manchester, 131 Princess Street, Manchester M1 7DN (United Kingdom)Search for more papers by this authorDr. Sam P. de Visser, Corresponding Author Dr. Sam P. de Visser sam.devisser@manchester.ac.uk Manchester Institute of Biotechnology and School of Chemical Engineering and Analytical Science, The University of Manchester, 131 Princess Street, Manchester M1 7DN (United Kingdom) Chivukula V. Sastri, Department of Chemistry, Indian Institute of Technology Guwahati, Assam, 781039 (India) Devesh Kumar, Department of Applied Physics, Babasaheb Bhimrao Ambedkar University, School for Physical Sciences, Vidya Vihar, Rae Bareilly Road, Lucknow (UP), 226025 (India) Sam P. de Visser, Manchester Institute of Biotechnology and School of Chemical Engineering and Analytical Science, The University of Manchester, 131 Princess Street, Manchester M1 7DN (United Kingdom)Search for more papers by this author Anil Kumar Vardhaman, Anil Kumar Vardhaman Department of Chemistry, Indian Institute of Technology Guwahati, Assam, 781039 (India)Search for more papers by this authorPrasenjit Barman, Prasenjit Barman Department of Chemistry, Indian Institute of Technology Guwahati, Assam, 781039 (India)Search for more papers by this authorSuresh Kumar, Suresh Kumar Department of Applied Physics, Babasaheb Bhimrao Ambedkar University, School for Physical Sciences, Vidya Vihar, Rae Bareilly Road, Lucknow (UP), 226025 (India)Search for more papers by this authorDr. Chivukula V. Sastri, Corresponding Author Dr. Chivukula V. Sastri sastricv@iitg.ernet.in Department of Chemistry, Indian Institute of Technology Guwahati, Assam, 781039 (India) Chivukula V. Sastri, Department of Chemistry, Indian Institute of Technology Guwahati, Assam, 781039 (India) Devesh Kumar, Department of Applied Physics, Babasaheb Bhimrao Ambedkar University, School for Physical Sciences, Vidya Vihar, Rae Bareilly Road, Lucknow (UP), 226025 (India) Sam P. de Visser, Manchester Institute of Biotechnology and School of Chemical Engineering and Analytical Science, The University of Manchester, 131 Princess Street, Manchester M1 7DN (United Kingdom)Search for more papers by this authorDr. Devesh Kumar, Corresponding Author Dr. Devesh Kumar dkclcre@yahoo.com Department of Applied Physics, Babasaheb Bhimrao Ambedkar University, School for Physical Sciences, Vidya Vihar, Rae Bareilly Road, Lucknow (UP), 226025 (India) Chivukula V. Sastri, Department of Chemistry, Indian Institute of Technology Guwahati, Assam, 781039 (India) Devesh Kumar, Department of Applied Physics, Babasaheb Bhimrao Ambedkar University, School for Physical Sciences, Vidya Vihar, Rae Bareilly Road, Lucknow (UP), 226025 (India) Sam P. de Visser, Manchester Institute of Biotechnology and School of Chemical Engineering and Analytical Science, The University of Manchester, 131 Princess Street, Manchester M1 7DN (United Kingdom)Search for more papers by this authorDr. Sam P. de Visser, Corresponding Author Dr. Sam P. de Visser sam.devisser@manchester.ac.uk Manchester Institute of Biotechnology and School of Chemical Engineering and Analytical Science, The University of Manchester, 131 Princess Street, Manchester M1 7DN (United Kingdom) Chivukula V. Sastri, Department of Chemistry, Indian Institute of Technology Guwahati, Assam, 781039 (India) Devesh Kumar, Department of Applied Physics, Babasaheb Bhimrao Ambedkar University, School for Physical Sciences, Vidya Vihar, Rae Bareilly Road, Lucknow (UP), 226025 (India) Sam P. de Visser, Manchester Institute of Biotechnology and School of Chemical Engineering and Analytical Science, The University of Manchester, 131 Princess Street, Manchester M1 7DN (United Kingdom)Search for more papers by this author First published: 25 September 2013 https://doi.org/10.1002/ange.201305370Citations: 23 † Research support was provided by the Department of Science and Technology, India (SR/S1/IC-02/2009) and Council for Scientific & Industrial Research (01(2527)/11/EMR-II) to C.V.S. The National Service of Computational Chemistry Software (NSCCS) is acknowledged for CPU time. D.K. acknowledges Department of Science and Technology (New Delhi) for a Ramanujan Fellowship. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Direkter Vergleich: Der erste detaillierte Reaktivitätsvergleich von Nicht-Häm-Eisen(IV)-Imido- und Nicht-Häm-Eisen(IV)-Oxo-Intermediaten mit Substraten ergab, dass die Eisen(IV)-Imido-Variante mit Sulfiden fünfmal schneller reagiert als ihr Eisen(IV)-Oxo-Pendant, während man bei der Wasserstoffatomabstraktion umgekehrte Verhältnisse beobachtet. Die Ergebnisse werden analysiert und erklärt. 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