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Quasi‐Elastic Neutron Scattering and Molecular Dynamics Study of Methane Diffusion in Metal Organic Frameworks MIL‐47(V) and MIL‐53(Cr)

2008; Wiley; Volume: 120; Issue: 35 Linguagem: Alemão

10.1002/ange.200801748

1521-3757

Nilton Rosenbach, Hervé Jobic, Aziz Ghoufi, Fabrice Salles, Guillaume Maurin, Sandrine Bourrelly, Philip L. Llewellyn, Thomas Devic, Christian Serre, Gérard Férey,

Crystallography and molecular interactions

Angewandte ChemieVolume 120, Issue 35 p. 6713-6717 Zuschrift Quasi-Elastic Neutron Scattering and Molecular Dynamics Study of Methane Diffusion in Metal Organic Frameworks MIL-47(V) and MIL-53(Cr)† Nilton Rosenbach Jr. Dr., Nilton Rosenbach Jr. Dr. Institut Charles Gerhardt Montpellier, Université Montpellier 2, Place E. Bataillon, 34095 Montpellier cedex 05 (France), Fax: (+33) 4-6714-4290Search for more papers by this authorHervé Jobic Dr., Hervé Jobic Dr. herve.jobic@ircelyon.univ-lyon1.fr Institut de Recherches sur la Catalyse et l'environnement de Lyon, Université de Lyon, CNRS, 2. Av. A. Einstein, 69626 Villeurbanne (France), Fax: (+33) 4-7244-5399Search for more papers by this authorAziz Ghoufi Dr., Aziz Ghoufi Dr. Institut Charles Gerhardt Montpellier, Université Montpellier 2, Place E. Bataillon, 34095 Montpellier cedex 05 (France), Fax: (+33) 4-6714-4290Search for more papers by this authorFabrice Salles Dr., Fabrice Salles Dr. Institut Charles Gerhardt Montpellier, Université Montpellier 2, Place E. Bataillon, 34095 Montpellier cedex 05 (France), Fax: (+33) 4-6714-4290Search for more papers by this authorGuillaume Maurin Dr., Guillaume Maurin Dr. gmaurin@lpmc.univ-montp2.fr Institut Charles Gerhardt Montpellier, Université Montpellier 2, Place E. Bataillon, 34095 Montpellier cedex 05 (France), Fax: (+33) 4-6714-4290Search for more papers by this authorSandrine Bourrelly Dr., Sandrine Bourrelly Dr. Laboratoire Chimie Provence, Universités d'Aix-Marseille I,II et III – CNRS, UMR 6264, Centre de Saint Jérôme, 13397 Marseille (France)Search for more papers by this authorPhilip L. Llewellyn Dr., Philip L. Llewellyn Dr. Laboratoire Chimie Provence, Universités d'Aix-Marseille I,II et III – CNRS, UMR 6264, Centre de Saint Jérôme, 13397 Marseille (France)Search for more papers by this authorThomas Devic Dr., Thomas Devic Dr. Institut Lavoisier, UMR CNRS 8180, Université de Versailles, Saint-Quentin-en-Yvelines, 78035 Versailles Cedex (France)Search for more papers by this authorChristian Serre Dr., Christian Serre Dr. Institut Lavoisier, UMR CNRS 8180, Université de Versailles, Saint-Quentin-en-Yvelines, 78035 Versailles Cedex (France)Search for more papers by this authorGérard Férey Prof., Gérard Férey Prof. Institut Lavoisier, UMR CNRS 8180, Université de Versailles, Saint-Quentin-en-Yvelines, 78035 Versailles Cedex (France)Search for more papers by this author Nilton Rosenbach Jr. Dr., Nilton Rosenbach Jr. Dr. Institut Charles Gerhardt Montpellier, Université Montpellier 2, Place E. Bataillon, 34095 Montpellier cedex 05 (France), Fax: (+33) 4-6714-4290Search for more papers by this authorHervé Jobic Dr., Hervé Jobic Dr. herve.jobic@ircelyon.univ-lyon1.fr Institut de Recherches sur la Catalyse et l'environnement de Lyon, Université de Lyon, CNRS, 2. Av. A. Einstein, 69626 Villeurbanne (France), Fax: (+33) 4-7244-5399Search for more papers by this authorAziz Ghoufi Dr., Aziz Ghoufi Dr. Institut Charles Gerhardt Montpellier, Université Montpellier 2, Place E. Bataillon, 34095 Montpellier cedex 05 (France), Fax: (+33) 4-6714-4290Search for more papers by this authorFabrice Salles Dr., Fabrice Salles Dr. Institut Charles Gerhardt Montpellier, Université Montpellier 2, Place E. Bataillon, 34095 Montpellier cedex 05 (France), Fax: (+33) 4-6714-4290Search for more papers by this authorGuillaume Maurin Dr., Guillaume Maurin Dr. gmaurin@lpmc.univ-montp2.fr Institut Charles Gerhardt Montpellier, Université Montpellier 2, Place E. Bataillon, 34095 Montpellier cedex 05 (France), Fax: (+33) 4-6714-4290Search for more papers by this authorSandrine Bourrelly Dr., Sandrine Bourrelly Dr. Laboratoire Chimie Provence, Universités d'Aix-Marseille I,II et III – CNRS, UMR 6264, Centre de Saint Jérôme, 13397 Marseille (France)Search for more papers by this authorPhilip L. Llewellyn Dr., Philip L. Llewellyn Dr. Laboratoire Chimie Provence, Universités d'Aix-Marseille I,II et III – CNRS, UMR 6264, Centre de Saint Jérôme, 13397 Marseille (France)Search for more papers by this authorThomas Devic Dr., Thomas Devic Dr. Institut Lavoisier, UMR CNRS 8180, Université de Versailles, Saint-Quentin-en-Yvelines, 78035 Versailles Cedex (France)Search for more papers by this authorChristian Serre Dr., Christian Serre Dr. Institut Lavoisier, UMR CNRS 8180, Université de Versailles, Saint-Quentin-en-Yvelines, 78035 Versailles Cedex (France)Search for more papers by this authorGérard Férey Prof., Gérard Férey Prof. Institut Lavoisier, UMR CNRS 8180, Université de Versailles, Saint-Quentin-en-Yvelines, 78035 Versailles Cedex (France)Search for more papers by this author First published: 08 August 2008 https://doi.org/10.1002/ange.200801748Citations: 22 † This work was supported by the French program ANR CO2 "NoMAC" (ANR-06-CO2-008) and European funding ALFA II "NANOGASTOR" (II-0493-FA-FI). We thank the Institut Laue-Langevin (Grenoble, France) for the neutron beam time, Dr. M. M. Koza for his help, and the CINES for computational facility. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Kanalflutung: Die Diffusion von Methan in den metall-organischen Gerüsten MIL-53(Cr) und MIL-47(V) wurde durch quasielastische Neutronenbeugung und Moleküldynamiksimulationen aufgeklärt; dabei wurde in beiden Materialien eine eindimensionale Diffusion von CH4 entlang der Kanäle beobachtet. Der Eigendiffusionskoeffizient von Methan bei niedriger Beladung liegt um mehr als eine Größenordnung über dem in Zeolithen. Das Bild zeigt CH4-Moleküle in einem MIL-53(Cr)-Kanal. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2008/z801748_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume120, Issue35August 18, 2008Pages 6713-6717 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation