Portal de Periódicos da CAPES

Mechanistic Studies on the Reaction between R 2 N‐NONOates and Aquacobalamin: Evidence for Direct Transfer of a Nitroxyl Group from R 2 N‐NONOates to Cobalt(III) Centers

2009; Wiley; Volume: 121; Issue: 47 Linguagem: Inglês

10.1002/ange.200904360

1521-3757

Hanaa A. Hassanin, Luciana Hannibal, Donald W. Jacobsen, M.F. El–Shahat, Mohamed S. A. Hamza, Nicola E. Brasch,

Advanced battery technologies research

Unglaubliche Geschichten: Das Übertragen einer Nitroxylgruppe von R2N-NONOaten auf Aquacobalamin, bei dem Nitroxylcobalamin entsteht, verläuft nicht über eine H+-katalysierte R2N-NONOat-Zersetzung, sondern wahrscheinlich über ein NONOat-Cobalamin-Intermediat (siehe Schema; r.d.s.=geschwindigkeitsbestimmender Schritt). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.