Atom‐Transfer Radical Reactions under Mild Conditions with [{RuCl 2 (1,3,5‐C 6 H 3 i Pr 3 )} 2 ] and PCy 3 as the Catalyst Precursors
2005; Wiley; Volume: 117; Issue: 7 Linguagem: Inglês
10.1002/ange.200462037
ISSN1521-3757
AutoresL. Quebatte, Michel Haas, Euro Solari, Rosario Scopelliti, Quoc Tuan Nguyen, Kay Severin,
Tópico(s)Advanced Photocatalysis Techniques
ResumoAngewandte ChemieVolume 117, Issue 7 p. 1108-1112 Zuschrift Atom-Transfer Radical Reactions under Mild Conditions with [{RuCl2(1,3,5-C6H3iPr3)}2] and PCy3 as the Catalyst Precursors† Laurent Quebatte, Laurent Quebatte Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland, Fax: (+41) 21-693-9305Search for more papers by this authorMichel Haas Dr., Michel Haas Dr. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland, Fax: (+41) 21-693-9305Search for more papers by this authorEuro Solari Dr., Euro Solari Dr. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland, Fax: (+41) 21-693-9305Search for more papers by this authorRosario Scopelliti Dr., Rosario Scopelliti Dr. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland, Fax: (+41) 21-693-9305Search for more papers by this authorQuoc T. Nguyen Dr., Quoc T. Nguyen Dr. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland, Fax: (+41) 21-693-9305 Institute of Materials, EPFL, 1015 Lausanne, SwitzerlandSearch for more papers by this authorKay Severin Prof., Kay Severin Prof. [email protected] Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland, Fax: (+41) 21-693-9305Search for more papers by this author Laurent Quebatte, Laurent Quebatte Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland, Fax: (+41) 21-693-9305Search for more papers by this authorMichel Haas Dr., Michel Haas Dr. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland, Fax: (+41) 21-693-9305Search for more papers by this authorEuro Solari Dr., Euro Solari Dr. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland, Fax: (+41) 21-693-9305Search for more papers by this authorRosario Scopelliti Dr., Rosario Scopelliti Dr. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland, Fax: (+41) 21-693-9305Search for more papers by this authorQuoc T. Nguyen Dr., Quoc T. Nguyen Dr. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland, Fax: (+41) 21-693-9305 Institute of Materials, EPFL, 1015 Lausanne, SwitzerlandSearch for more papers by this authorKay Severin Prof., Kay Severin Prof. [email protected] Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland, Fax: (+41) 21-693-9305Search for more papers by this author First published: 01 February 2005 https://doi.org/10.1002/ange.200462037Citations: 7 † This work was supported by a postdoctoral fellowship from the Ministère de la Culture, de l'Enseignement Supérieur et de la Recherche, Luxembourg (M.H.) and by the Swiss National Science Foundation. We thank Prof. Harm-Anton Klok (EPFL) for his support with the GPC measurements. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Einfaches Mischen des Komplexes [{RuCl2(1,3,5-C6H3iPr3)}2] (1) mit PCy3 liefert einen Katalysator, der bei außergewöhnlich niedrigen Temperaturen Atomtransfer-Radikalpolymerisationen und -additionen hoch effizient katalysiert (siehe Schema). Die sterische Überladung am Metall als Folge der sperrigen Liganden wird als entscheidend für die Reaktivität des Katalysators gesehen. 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