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BIBTEX RIS

Photochemical Activation of the N≡N Bond in a Dimolybdenum-Dinitrogen Complex: Formation of a Molybdenum Nitride

2001; Wiley; Volume: 40; Issue: 20 Linguagem: Inglês

10.1002/1521-3773(20011015)40

ISSN

1521-3773

Autores

Euro Solari, Carlos Da Silva, Barbara Iacono, J. Hesschenbrouck, Corrado Rizzoli, Rosario Scopelliti, Carlo Floriani,

Tópico(s)

Inorganic Chemistry and Materials

Resumo

Photoinduced cleavage of the residual N-N bond in the dimetallahydrazone 1 (Mes=2,4,6-Me3 C6 H2 ) led to a transient monomeric nitrido complex, which reacts further with 1 to form 2. Compound 1 was synthesized by the reductive arylation of MoCl4 ⋅DME by MesMgBr under an N2 atmosphere.

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