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Distribution Behavior of Pyrene to Adsorbed Humic Acids on Kaolin

2003; Wiley; Volume: 32; Issue: 2 Linguagem: Inglês

10.2134/jeq2003.0591

1537-2537

Motoki Terashima, Shunitz Tanaka, Masami Fukushima,

Methane Hydrates and Related Phenomena

Journal of Environmental QualityVolume 32, Issue 2 p. 591-598 Organic Compound in the Environment Distribution Behavior of Pyrene to Adsorbed Humic Acids on Kaolin Motoki Terashima, Motoki Terashima Division of Material Science, Graduate School of Environmental Earth Science, Hokkaido Univ., Sapporo, 060-0810 JapanSearch for more papers by this authorShunitz Tanaka, Corresponding Author Shunitz Tanaka [email protected] Division of Material Science, Graduate School of Environmental Earth Science, Hokkaido Univ., Sapporo, 060-0810 JapanCorresponding author ([email protected])Search for more papers by this authorMasami Fukushima, Masami Fukushima National Institute of Advanced Industrial Science and Technology (AIST), 16-1 Onogawa, Tsukuba, 305-8569 JapanSearch for more papers by this author Motoki Terashima, Motoki Terashima Division of Material Science, Graduate School of Environmental Earth Science, Hokkaido Univ., Sapporo, 060-0810 JapanSearch for more papers by this authorShunitz Tanaka, Corresponding Author Shunitz Tanaka [email protected] Division of Material Science, Graduate School of Environmental Earth Science, Hokkaido Univ., Sapporo, 060-0810 JapanCorresponding author ([email protected])Search for more papers by this authorMasami Fukushima, Masami Fukushima National Institute of Advanced Industrial Science and Technology (AIST), 16-1 Onogawa, Tsukuba, 305-8569 JapanSearch for more papers by this author First published: 01 March 2003 https://doi.org/10.2134/jeq2003.5910Citations: 24Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat ABSTRACT The distribution behavior of pyrene on humic acid (HA)–kaolin complexes, prepared by adsorbing HA on kaolin, was investigated by batch experiments. The distribution coefficient (Kd) of pyrene on the HA–kaolin complex increased with the fraction (foc) of organic carbon adsorbed to the surface of the kaolin. This can be attributed to hydrophobic interactions between pyrene and the adsorbed HAs. The effects of adsorbed HAs were quantitatively evaluated by calculating the distribution coefficient (Koc) and affinity constant (Kadsoc) for pyrene to the adsorbed HAs. A fluorescence quenching method was employed to determine the affinity constant (Kaqoc) of pyrene to HAs dissolved in an aqueous solution. When the Koc values were compared with the Kaqoc values, the Koc values were found to be 4 to 11 times larger than the Kaqoc values. On the other hand, the Kadsoc values were 4 to 9 times larger than the Kaqoc values. These indicate that the affinity for pyrene is enhanced by the adsorption of HAs to kaolin. In addition, the Koc values increased with increasing average molecular weights of the HAs. These results demonstrate that HAs, when they are adsorbed to clay minerals, play an important role in the deposition of polycyclic aromatic hydrocarbons (PAHs) in a soil environment. References B.J. Alloway, and and D.C. Ayres (ed.) 1993. Chemical principles of environmental pollution. Blackie Academic & Professional, Glasgow, UK. 10.1007/978-94-011-2148-4 Web of Science®Google Scholar Chin, Y.-P. Molecular weight, polydispersity, and spectroscopic properties of aquatic humic substances. Environ. Sci. 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