Silicon–Carbon and Silicon–Nitrogen Multiply Bonded Compounds
1998; Wiley; Linguagem: Inglês
10.1002/0470857250.ch16
ISSN2042-5651
AutoresThomas Müller, Wolfgang Ziche, Norbert Auner,
Tópico(s)Organoselenium and organotellurium chemistry
ResumoChapter 16 Silicon–Carbon and Silicon–Nitrogen Multiply Bonded Compounds Thomas Müller, Thomas Müller h0443afs@joker.rz.hu-berlin.de Fachinstitut für Anorganische und Allgemeine Chemie, Humboldt Universität zu Berlin, Hessische Str. 1–2, D-10115 Berlin, Germany. Fax: +49-30-20936966Search for more papers by this authorWolfgang Ziche, Wolfgang Ziche ziche@chemie.hu-berlin.de Fachinstitut für Anorganische und Allgemeine Chemie, Humboldt Universität zu Berlin, Hessische Str. 1–2, D-10115 Berlin, Germany. Fax: +49-30-20936966Search for more papers by this authorNorbert Auner, Norbert Auner auner@chemie.hu-berlin.de Fachinstitut für Anorganische und Allgemeine Chemie, Humboldt Universität zu Berlin, Hessische Str. 1–2, D-10115 Berlin, Germany. Fax: +49-30-20936966Search for more papers by this author Thomas Müller, Thomas Müller h0443afs@joker.rz.hu-berlin.de Fachinstitut für Anorganische und Allgemeine Chemie, Humboldt Universität zu Berlin, Hessische Str. 1–2, D-10115 Berlin, Germany. Fax: +49-30-20936966Search for more papers by this authorWolfgang Ziche, Wolfgang Ziche ziche@chemie.hu-berlin.de Fachinstitut für Anorganische und Allgemeine Chemie, Humboldt Universität zu Berlin, Hessische Str. 1–2, D-10115 Berlin, Germany. Fax: +49-30-20936966Search for more papers by this authorNorbert Auner, Norbert Auner auner@chemie.hu-berlin.de Fachinstitut für Anorganische und Allgemeine Chemie, Humboldt Universität zu Berlin, Hessische Str. 1–2, D-10115 Berlin, Germany. Fax: +49-30-20936966Search for more papers by this author Book Editor(s):Zvi Rappoport, Zvi Rappoport The Hebrew University, Jerusalem, IsraelSearch for more papers by this authorYitzhak Apeloig, Yitzhak Apeloig Department of Chemistry and the Lise-Meitner Minerva Center for Computational Quantum Chemistry, Technion–Israel Institute of Technology, Haifa 32000, IsraelSearch for more papers by this author First published: 30 July 1998 https://doi.org/10.1002/0470857250.ch16Citations: 46Book Series:PATAI'S Chemistry of Functional Groups Series Editor(s): Zvi Rappoport, Zvi Rappoport The Hebrew University, Jerusalem, IsraelSearch for more papers by this author AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Summary This chapter contains sections titled: Silenes Synthesis Cycloreversion Reactions Salt Elimination Donor Cleavage Isomerization of Acylpolysilanes Silenes by the Sila-Peterson Reaction Reaction of Silyllithium Reagents with Ketones or Aldehydes Reaction of Polysilylacylsilanes with Organometallic Reagents Deprotonation of Polysilylcarbinols Reaction of 2-siloxysilenes with Organometallic Reagents Photolysis of Disilanes Silenes by Rearrangement of Silylenes and Carbenes Other Group 14 Carbon Double Bonded Species Reactivity Rearrangements Silene-to-silylene Interconversions Silene-to-silene Isomerization Intramolecular Insertion Reactions Dimerizations Head-to-head Dimerization Head-to-tail Dimerization Nucleophilic Additions Reaction with Alcohols Reaction with Alkoxysilanes Reaction with Organometallic Reagents Cycloaddition Reactions Wiberg-type Silenes Me2SiC(SiMe3)2 [2 + 2] Cycloaddition Reactions [2 + 4] Cycloaddition and Ene Reactions [2 + 3] Cycloaddition Reactions Ph2SiC(SiMe3)2 t-Bu2SiC(SiMe3)2(104), Me2SiC(SiMe3)[SiMe(t-Bu)2] (104a) and 104a·Donor Neopentylsilenes: R2SiC(R′)CH2Bu-t Diorgano-substituted Neopentylsilenes π-donor-substituted Neopentylsilenes Brook-type Silenes [2 + 1] Cycloaddition Reactions Cycloadditions with Alkenes, Dienes and Alkynes Apeloig–Ishikawa–Oehme-type Silenes Cycloaddition Reactions with Carbonyl Compounds and Derivatives Miscellaneous Silenes [2 + 2] Cycloaddition Reactions [2 + 3] Cycloaddition Reactions [2 + 4] Cycloaddition Reactions Ene Reactions Oxidations Miscellaneous Structure and Spectroscopic Properties of Silenes Structural Studies 29Si and 13C NMR Spectroscopic Data 29Si NMR Spectroscopy 13C NMR Spectroscopy Infrared Spectroscopic Data UV Spectroscopic Data Miscellaneous Silaallenes Theoretical Studies Synthesis Reactivity 1-silaallenes 2-silaallenes SiC Triply Bonded Compounds: Theoretical Results Silicon–Nitrogen Multiply Bonded Compounds Introduction Synthesis SiN and SiN Systems Salt Elimination Cycloreversion Reactions Photolysis and Pyrolysis of Silyl Azides Retro-ene Reactions Dehydrochlorination Silylene Addition to Azides Reaction of SiH4 and N2 Ionic SiN Compounds by Gas Phase Reactions Silicon-containing Anions [HSiNH]−: An Anion Related to Silanimine H2SiNH Silaformamide Ion [HSi(O)NH]− Silicon-containing Cations NSiN Systems Silanediimines Silaamidides [(RN)2SiR′]− SiN Metal Systems Reactivity Donor Addition Insertion Reactions Ene Reactions Cycloaddition Reactions [2 + 2] Cycloadditions [2 + 3] Cycloadditions [2 + 4] Cycloadditions Metal Silanimine Complexes X-ray Structures Spectroscopy NMR Spectroscopy IR and UV-Vis Spectroscopy Miscellaneous Theoretical Studies GeN, SiP and SiAs Multiply Bonded Species and Related Compounds Acknowledgements References Citing Literature The Chemistry of Organic Silicon Compounds, Volume 2 RelatedInformation
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