Voltar
Artigo Revisado por pares
BIBTEX RIS

Ferromagnetic Ordering in a Diamond-Like Cyano-Bridged MnIIRuIII Bimetallic Coordination Polymer

2001; Wiley; Volume: 40; Issue: 16 Linguagem: Inglês

10.1002/1521-3773(20010817)40

ISSN

1521-3773

Autores

W Yeung, Wai‐Lun Man, Wing‐Tak Wong, Tai‐Chu Lau, Song Gao,

Tópico(s)

Metal complexes synthesis and properties

Resumo

Cyano-mediated interaction of the alternating high-spin Mn(II) centers and low-spin Ru(III) centers in {Mn[Ru(acac)2 (CN)2 ]2 }n (Hacac=acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel Mn(II) Ru(III) coordination polymer, which has a diamond-like structure, was constructed from [Ru(acac)2 (CN)2 ](-) and Mn(2+) ions.

Referência(s)