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Catalytic Asymmetric Synthesis of Tertiary Alkyl Chlorides

2007; Wiley; Volume: 119; Issue: 6 Linguagem: Inglês

10.1002/ange.200604312

1521-3757

Elaine C. Lee, Kevin M. McCauley, Gregory C. Fu,

Synthesis and Reactions of Organic Compounds

Angewandte ChemieVolume 119, Issue 6 p. 995-997 Zuschrift Catalytic Asymmetric Synthesis of Tertiary Alkyl Chlorides† Elaine C. Lee, Elaine C. Lee Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA, Fax: (+1) 617-324-3611Search for more papers by this authorKevin M. McCauley Dr., Kevin M. McCauley Dr. Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA, Fax: (+1) 617-324-3611Search for more papers by this authorGregory C. Fu Prof. Dr., Gregory C. Fu Prof. Dr. gcf@mit.edu Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA, Fax: (+1) 617-324-3611Search for more papers by this author Elaine C. Lee, Elaine C. Lee Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA, Fax: (+1) 617-324-3611Search for more papers by this authorKevin M. McCauley Dr., Kevin M. McCauley Dr. Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA, Fax: (+1) 617-324-3611Search for more papers by this authorGregory C. Fu Prof. Dr., Gregory C. Fu Prof. Dr. gcf@mit.edu Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA, Fax: (+1) 617-324-3611Search for more papers by this author First published: 22 January 2007 https://doi.org/10.1002/ange.200604312Citations: 19 † We thank Michael Choi for preliminary studies and Luke Firmansjah and Dr. Peter Mueller for an X-ray crystallographic investigation. Support has been provided by the NIH (National Institute of General Medical Sciences: R01-GM57034 and F32-GM069154 (fellowship for K.M.M.); National Cancer Institute (training grant CA009112), Merck, and Novartis. Funding for the MIT Department of Chemistry Instrumentation Facility has been furnished in part by NSF CHE-9808061 and NSF DBI-9729592. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Ketene werden in einer katalytischen asymmetrischen Synthese tertiärer α-Chlorester mit 2,2,6,6-Tetrachlorcyclohexanon gekuppelt (siehe Schema). Diese Methode ergänzt kürzlich bei der Erzeugung sekundärer α-Halogencarbonylverbindungen erzielte Fortschritte. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2007/z604312_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume119, Issue6January 29, 2007Pages 995-997 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation