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Chiral Iridium Catalysts Bearing Spiro Pyridine‐Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of β ‐ Aryl β‐Ketoesters

2011; Wiley; Volume: 124; Issue: 1 Linguagem: Inglês

10.1002/ange.201105780

1521-3757

Jian‐Hua Xie, Xiaoyan Liu, Xiao‐Hui Yang, Jian‐Bo Xie, Lixin Wang, Qi‐Lin Zhou,

Asymmetric Synthesis and Catalysis

Angewandte ChemieVolume 124, Issue 1 p. 205-207 Zuschrift Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of β-Aryl β-Ketoesters† Prof. Jian-Hua Xie, Corresponding Author Prof. Jian-Hua Xie jhxie@nankai.edu.cn State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)Search for more papers by this authorXiao-Yan Liu, Xiao-Yan Liu State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)Search for more papers by this authorXiao-Hui Yang, Xiao-Hui Yang State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)Search for more papers by this authorJian-Bo Xie, Jian-Bo Xie State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)Search for more papers by this authorProf. Li-Xin Wang, Prof. Li-Xin Wang State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)Search for more papers by this authorProf. Qi-Lin Zhou, Corresponding Author Prof. Qi-Lin Zhou qlzhou@nankai.edu.cn State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)Search for more papers by this author Prof. Jian-Hua Xie, Corresponding Author Prof. Jian-Hua Xie jhxie@nankai.edu.cn State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)Search for more papers by this authorXiao-Yan Liu, Xiao-Yan Liu State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)Search for more papers by this authorXiao-Hui Yang, Xiao-Hui Yang State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)Search for more papers by this authorJian-Bo Xie, Jian-Bo Xie State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)Search for more papers by this authorProf. Li-Xin Wang, Prof. Li-Xin Wang State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)Search for more papers by this authorProf. Qi-Lin Zhou, Corresponding Author Prof. Qi-Lin Zhou qlzhou@nankai.edu.cn State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)Search for more papers by this author First published: 16 November 2011 https://doi.org/10.1002/ange.201105780Citations: 30 † We thank the National Natural Science Foundation of China, the National Basic Research Program of China (2010CB833300), and the "111" project (B06005) of the Ministry of Education of China for financial support. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Unverwüstliche Katalyse: Chirale Iridiumkomplexe mit dem Liganden 1 katalysieren die asymmetrische Hydrierung von β-substituierten β-Ketoestern hoch effizient. Die β-Hydroxyester entstehen in hohen Ausbeuten mit ausgezeichneten Enantioselektivitäten und hohen Wechselzahlen (TONs). cod=1,5-Cyclooctadien. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_201105780_sm_miscellaneous_information.pdf936.5 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume124, Issue1January 2, 2012Pages 205-207 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation