Spontaneous Deracemization of Disc‐like Molecules in the Columnar Phase
2009; Wiley; Volume: 122; Issue: 2 Linguagem: Inglês
10.1002/ange.200904819
ISSN1521-3757
AutoresHiroki Nagayama, Sanjay K. Varshney, Masanao Goto, Fumito Araoka, Ken Ishikawa, Veena Prasad, Hideo Takezoe,
Tópico(s)Synthesis and Properties of Aromatic Compounds
ResumoAngewandte ChemieVolume 122, Issue 2 p. 455-458 Zuschrift Spontaneous Deracemization of Disc-like Molecules in the Columnar Phase Hiroki Nagayama, Hiroki Nagayama Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-Okayama, Meguro-ku, Tokyo, 152-8552 (Japan), Fax: (+81) 3-5734-2876Search for more papers by this authorSanjay Kumar Varshney, Sanjay Kumar Varshney Centre for Liquid Crystal Research, Post Box No. 1329, Jalahall, Bangalore, 560013 (India)Search for more papers by this authorMasanao Goto Dr., Masanao Goto Dr. Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-Okayama, Meguro-ku, Tokyo, 152-8552 (Japan), Fax: (+81) 3-5734-2876Search for more papers by this authorFumito Araoka Dr., Fumito Araoka Dr. Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-Okayama, Meguro-ku, Tokyo, 152-8552 (Japan), Fax: (+81) 3-5734-2876Search for more papers by this authorKen Ishikawa Prof. Dr., Ken Ishikawa Prof. Dr. Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-Okayama, Meguro-ku, Tokyo, 152-8552 (Japan), Fax: (+81) 3-5734-2876Search for more papers by this authorVeena Prasad Dr., Veena Prasad Dr. Centre for Liquid Crystal Research, Post Box No. 1329, Jalahall, Bangalore, 560013 (India)Search for more papers by this authorHideo Takezoe Prof. Dr., Hideo Takezoe Prof. Dr. [email protected] Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-Okayama, Meguro-ku, Tokyo, 152-8552 (Japan), Fax: (+81) 3-5734-2876Search for more papers by this author Hiroki Nagayama, Hiroki Nagayama Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-Okayama, Meguro-ku, Tokyo, 152-8552 (Japan), Fax: (+81) 3-5734-2876Search for more papers by this authorSanjay Kumar Varshney, Sanjay Kumar Varshney Centre for Liquid Crystal Research, Post Box No. 1329, Jalahall, Bangalore, 560013 (India)Search for more papers by this authorMasanao Goto Dr., Masanao Goto Dr. Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-Okayama, Meguro-ku, Tokyo, 152-8552 (Japan), Fax: (+81) 3-5734-2876Search for more papers by this authorFumito Araoka Dr., Fumito Araoka Dr. Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-Okayama, Meguro-ku, Tokyo, 152-8552 (Japan), Fax: (+81) 3-5734-2876Search for more papers by this authorKen Ishikawa Prof. Dr., Ken Ishikawa Prof. Dr. Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-Okayama, Meguro-ku, Tokyo, 152-8552 (Japan), Fax: (+81) 3-5734-2876Search for more papers by this authorVeena Prasad Dr., Veena Prasad Dr. Centre for Liquid Crystal Research, Post Box No. 1329, Jalahall, Bangalore, 560013 (India)Search for more papers by this authorHideo Takezoe Prof. Dr., Hideo Takezoe Prof. Dr. [email protected] Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-Okayama, Meguro-ku, Tokyo, 152-8552 (Japan), Fax: (+81) 3-5734-2876Search for more papers by this author First published: 28 December 2009 https://doi.org/10.1002/ange.200904819Citations: 14Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Chirale Scheiben: Scheinbar flache scheibenförmige Moleküle bilden eine columnare Phase und trennen sich spontan in makroskopische chirale Domänen (Deracemisierung). Quantenchemische Rechnungen legen einen verdrillten axial-chiralen Kern dieser Moleküle nahe (siehe Bild). Das Zusammenlagern zu chiralen Überstrukturen wird in elektronischen und Schwingungs-Circulardichroismus-Spektren offensichtlich. Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_200904819_sm_miscellaneous_information.pdf236 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. 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