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Nonmetal‐Mediated Fragmentation of P 4 : Isolation of P 1 and P 2 Bis(carbene) Adducts

2009; Wiley; Volume: 121; Issue: 30 Linguagem: Inglês

10.1002/ange.200902344

1521-3757

O. Back, G. Kuchenbeiser, B. Donnadieu, Guy Bertrand,

Organometallic Complex Synthesis and Catalysis

Angewandte ChemieVolume 121, Issue 30 p. 5638-5641 Zuschrift Nonmetal-Mediated Fragmentation of P4: Isolation of P1 and P2 Bis(carbene) Adducts† Olivier Back, Olivier Back UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/Search for more papers by this authorGlenn Kuchenbeiser, Glenn Kuchenbeiser UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/Search for more papers by this authorBruno Donnadieu, Bruno Donnadieu UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/Search for more papers by this authorGuy Bertrand Prof., Guy Bertrand Prof. [email protected] UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/Search for more papers by this author Olivier Back, Olivier Back UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/Search for more papers by this authorGlenn Kuchenbeiser, Glenn Kuchenbeiser UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/Search for more papers by this authorBruno Donnadieu, Bruno Donnadieu UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/Search for more papers by this authorGuy Bertrand Prof., Guy Bertrand Prof. [email protected] UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/Search for more papers by this author First published: 08 July 2009 https://doi.org/10.1002/ange.200902344Citations: 144 † Financial support from the NSF (CHE 0808825) and Rhodia Inc. are gratefully acknowledged. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract P4 stückweise: Stabile Singulettcarbene reagieren mit weißem Phosphor bei Raumtemperatur unter Bildung von P4-, P3-, P2- und sogar P1-Fragmenten, die durch die Carbeneinheit stabilisiert werden (siehe Bild). Diese Folge aus Aktivierung und Fragmentierung, die bislang den Einsatz von Übergangsmetallen erforderte, könnte auf umweltverträglicherem Weg zu Phosphorverbindungen führen. Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_200902344_sm_miscellaneous_information.pdf166.2 KB miscellaneous information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1For recent examples of small molecule activation by nonmetals other than carbenes, see: Google Scholar 1aS. J. Geier, D. W. Stephan, J. Am. Chem. Soc. 2009, 131, 3476–3477; 10.1021/ja900572x CASPubMedWeb of Science®Google Scholar 1bM. Ullrich, A. J. Lough, D. W. Stephan, J. Am. Chem. Soc. 2009, 131, 52–53; 10.1021/ja808506t CASPubMedWeb of Science®Google Scholar 1cS. N. Riduan, Y. Zhang, J. Y. Ying, Angew. 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