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Controlling Chirality and Optical Properties of Artificial Antenna Systems with Self‐Assembling Porphyrins

2003; Wiley; Volume: 115; Issue: 19 Linguagem: Inglês

10.1002/ange.200250465

1521-3757

Teodor Silviu Balaban, Anil Dnyanoba Bhise, Matthias Fischer, Myriam Linke‐Schaetzel, Christian Roussel, Nicholas Vanthuyne,

Porphyrin Metabolism and Disorders

Angewandte ChemieVolume 115, Issue 19 p. 2190-2194 Zuschrift Controlling Chirality and Optical Properties of Artificial Antenna Systems with Self-Assembling Porphyrins† Teodor Silviu Balaban Priv. Doz. Dr., Teodor Silviu Balaban Priv. Doz. Dr. silviu.balaban@int.fzk.de Institut für Nanotechnologie, Forschungszentrum Karlsruhe, Postfach 3640, 76021 Karlsruhe, Germany, Fax: (+49) 724-782-6434Search for more papers by this authorAnil Dnyanoba Bhise, Anil Dnyanoba Bhise Institut für Nanotechnologie, Forschungszentrum Karlsruhe, Postfach 3640, 76021 Karlsruhe, Germany, Fax: (+49) 724-782-6434Search for more papers by this authorMatthias Fischer, Matthias Fischer Institut für Nanotechnologie, Forschungszentrum Karlsruhe, Postfach 3640, 76021 Karlsruhe, Germany, Fax: (+49) 724-782-6434Search for more papers by this authorMyriam Linke-Schaetzel Dr., Myriam Linke-Schaetzel Dr. Institut für Nanotechnologie, Forschungszentrum Karlsruhe, Postfach 3640, 76021 Karlsruhe, Germany, Fax: (+49) 724-782-6434Search for more papers by this authorChristian Roussel Prof. Dr., Christian Roussel Prof. Dr. ENSSPICAM Université, Centre de Saint Jerome, 13397 Marseille CEDEX 20, FranceSearch for more papers by this authorNicholas Vanthuyne Dr., Nicholas Vanthuyne Dr. ENSSPICAM Université, Centre de Saint Jerome, 13397 Marseille CEDEX 20, FranceSearch for more papers by this author Teodor Silviu Balaban Priv. Doz. Dr., Teodor Silviu Balaban Priv. Doz. Dr. silviu.balaban@int.fzk.de Institut für Nanotechnologie, Forschungszentrum Karlsruhe, Postfach 3640, 76021 Karlsruhe, Germany, Fax: (+49) 724-782-6434Search for more papers by this authorAnil Dnyanoba Bhise, Anil Dnyanoba Bhise Institut für Nanotechnologie, Forschungszentrum Karlsruhe, Postfach 3640, 76021 Karlsruhe, Germany, Fax: (+49) 724-782-6434Search for more papers by this authorMatthias Fischer, Matthias Fischer Institut für Nanotechnologie, Forschungszentrum Karlsruhe, Postfach 3640, 76021 Karlsruhe, Germany, Fax: (+49) 724-782-6434Search for more papers by this authorMyriam Linke-Schaetzel Dr., Myriam Linke-Schaetzel Dr. Institut für Nanotechnologie, Forschungszentrum Karlsruhe, Postfach 3640, 76021 Karlsruhe, Germany, Fax: (+49) 724-782-6434Search for more papers by this authorChristian Roussel Prof. Dr., Christian Roussel Prof. Dr. ENSSPICAM Université, Centre de Saint Jerome, 13397 Marseille CEDEX 20, FranceSearch for more papers by this authorNicholas Vanthuyne Dr., Nicholas Vanthuyne Dr. ENSSPICAM Université, Centre de Saint Jerome, 13397 Marseille CEDEX 20, FranceSearch for more papers by this author First published: 14 May 2003 https://doi.org/10.1002/ange.200250465Citations: 45 † This work was partially supported by the Deutsche Forschungsgemeinschaft (DFG) through the joint project C3.2 of the Center for Functional Nanostructures involving FZK-INT and the University of Karlsruhe. We thank Prof. Horst Hahn and Dr. Branko Stahl for the preparation of nanocrystalline TiO2, Dr. Hartmut Gliemann and Dr. Thomas Koch for fluorescence microscopic and AFM images, Prof. Volker Buß and Robert Knierim for CD measurements, Dr. Sergei Lebedkin for fluorescence spectra, Angelika Kernert and Ingrid Roßnagel for HR-FAB mass spectra. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Porphyrine mit naturidentischen Substituenten: Die gleichen Gruppen, die die Selbstorganisation des Bacteriochlorophylls in den Antennensystemen grüner Photosynthesebakterien vermitteln, erfüllen diese Funktion auch als Substituenten an vollsynthetischen Porphyrinen. Die Struktur der Monomere bestimmt hierbei Chiralität und optische Eigenschaften der tetrameren Aggregate (siehe Bild). Die Fluoreszenzeigenschaften der Aggregate werden weder durch Zusammenlagerung noch durch Chemisorption auf Titandioxid beeinträchtigt, sodass eine Verwendung in farbstoffsensitivierten Solarzellen möglich erscheint. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2003/z50465_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume115, Issue19May 16, 2003Pages 2190-2194 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation