Reactions of Macromolecules
2005; American Chemical Society; Linguagem: Inglês
10.1002/9783527627219.ch15
ISSN1520-5835
Autores Tópico(s)Analytical Chemistry and Chromatography
ResumoChapter 15 Reactions of Macromolecules Hans-Georg Elias, Hans-Georg EliasSearch for more papers by this author Hans-Georg Elias, Hans-Georg EliasSearch for more papers by this author Hans-Georg Elias, Hans-Georg EliasSearch for more papers by this author Book Author(s):Hans-Georg Elias, Hans-Georg EliasSearch for more papers by this author First published: 17 October 2005 https://doi.org/10.1002/9783527627219.ch15 AboutPDFPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShareShare a linkShare onEmailFacebookTwitterLinkedInRedditWechat Summary Macromolecules are reacted with low or high molecular weight chemical compounds in order to determine the chemical structure, modify the composition, or remove unwanted molecules. This chapter discusses catalyses, isomerizations, polymer-analog reactions, and degradation reactions. Polymer catalysts are expected to have three advantages over their low-molecular weight counterparts: greater selectivity of substrates, increased specificity with respect to the type of reaction, and better separability of reaction products. Isomerizations comprise exchange equilibria between molecular segments. Isomerizations may occur on formation of charge-transfer complexes of polydienes with sulfur or selenium. Polymer analog reactions are classic polymer transformations where poly(C) is the desired endproduct of the reaction of poly(A) with B. The chapter describes the basics of degradations. Chain scissions and depolymerizations without side reactions can only be expected at relatively low temperatures. Additional reactions occur at elevated temperatures, especially reactions of substitutents, leading to degradation in the common sense. Literature to Chapter 15 15.1 OVERVIEWS Google Scholar E.M. 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