Facile Synthetic Methods for the Diversification of Catena‐Polyphosphorus Cations
2005; Wiley; Volume: 117; Issue: 16 Linguagem: Inglês
10.1002/ange.200462997
ISSN1521-3757
AutoresNeil Burford, C. Adam Dyker, A. Decken,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoAngewandte ChemieVolume 117, Issue 16 p. 2416-2419 Zuschrift Facile Synthetic Methods for the Diversification of Catena-Polyphosphorus Cations† Neil Burford Prof., Neil Burford Prof. [email protected] Department of Chemistry, Dalhousie University, Halifax, NS B3H 4J3, Canada, Fax: (+1) 902-494-1310Search for more papers by this authorC. Adam Dyker, C. Adam Dyker Department of Chemistry, Dalhousie University, Halifax, NS B3H 4J3, Canada, Fax: (+1) 902-494-1310Search for more papers by this authorAndreas Decken Dr., Andreas Decken Dr. Department of Chemistry, University of New Brunswick, Fredericton, NB E3B 6E2, CanadaSearch for more papers by this author Neil Burford Prof., Neil Burford Prof. [email protected] Department of Chemistry, Dalhousie University, Halifax, NS B3H 4J3, Canada, Fax: (+1) 902-494-1310Search for more papers by this authorC. Adam Dyker, C. Adam Dyker Department of Chemistry, Dalhousie University, Halifax, NS B3H 4J3, Canada, Fax: (+1) 902-494-1310Search for more papers by this authorAndreas Decken Dr., Andreas Decken Dr. Department of Chemistry, University of New Brunswick, Fredericton, NB E3B 6E2, CanadaSearch for more papers by this author First published: 13 April 2005 https://doi.org/10.1002/ange.200462997Citations: 29 † We thank the Natural Sciences and Engineering Research Council of Canada, the Killam Foundation, the Canada Research Chairs Program, the Canada Foundation for Innovation, the Nova Scotia Research and Innovation Trust Fund, and the Walter C. Sumner Memorial Fellowship for funding; the Atlantic Region Magnetic Resonance Centre for use of instrumentation; Dr. M. Lumsden for assistance with the NMR spectroscopic data; and Dr. P. J. Ragogna and D. E. Herbert for preliminary experimental observations. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Zahl und Variabilität von Polyphosphor-Kationen sind deutlich geringer als die ihrer neutralen (Polyphosphine) und anionischen Analoga (Polyphosphide). Hier wird nun eine allgemeine und einfache Methode zur Synthese von Phosphanylphosphonium-, Diphosphanylphosphonium- und Cyclotetraphosphanylphosphonium-Ionen aus Polyphosphanen vorgestellt. Zudem wird die Stabilität des Cyclopentaphosphor-Rings betont (siehe Kristallstruktur von [Ph6P5]+). References 1M. Baudler, K. 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