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CH 3 ReO 3 on γ‐Al 2 O 3 : Understanding Its Structure, Initiation, and Reactivity in Olefin Metathesis

2007; Wiley; Volume: 119; Issue: 21 Linguagem: Inglês

10.1002/ange.200700211

1521-3757

Alain Salameh, Jérôme Joubert, Anne Baudouin, Wayne W. Lukens, Françoise Delbecq, Philippe Sautet, Jean‐Marie Basset, Christophe Copéret,

Catalytic Cross-Coupling Reactions

Angewandte ChemieVolume 119, Issue 21 p. 3944-3947 Zuschrift CH3ReO3 on γ-Al2O3: Understanding Its Structure, Initiation, and Reactivity in Olefin Metathesis† Alain Salameh Dr., Alain Salameh Dr. C2P2 Laboratoire de Chimie Organométallique de Surface, UMR 5265 CNRS—ESCPE Lyon, 43 Bd du 11 Novembre 1918, 69616 Villeurbanne Cedex, France, Fax: (+33) 472-431-795Search for more papers by this authorJérôme Joubert Dr., Jérôme Joubert Dr. Laboratoire de Chimie, Institut de Chimie de Lyon, Ecole normale supérieure de Lyon, CNRS, 46 allée d'Italie, 69364 Lyon Cedex 07, France, Fax: (+33) 472-728-860Search for more papers by this authorAnne Baudouin, Anne Baudouin C2P2 Laboratoire de Chimie Organométallique de Surface, UMR 5265 CNRS—ESCPE Lyon, 43 Bd du 11 Novembre 1918, 69616 Villeurbanne Cedex, France, Fax: (+33) 472-431-795Search for more papers by this authorWayne Lukens Dr., Wayne Lukens Dr. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USASearch for more papers by this authorFrançoise Delbecq Dr., Françoise Delbecq Dr. Laboratoire de Chimie, Institut de Chimie de Lyon, Ecole normale supérieure de Lyon, CNRS, 46 allée d'Italie, 69364 Lyon Cedex 07, France, Fax: (+33) 472-728-860Search for more papers by this authorPhilippe Sautet Dr., Philippe Sautet Dr. philippe.sautet@ens-lyon.fr Laboratoire de Chimie, Institut de Chimie de Lyon, Ecole normale supérieure de Lyon, CNRS, 46 allée d'Italie, 69364 Lyon Cedex 07, France, Fax: (+33) 472-728-860Search for more papers by this authorJean Marie Basset Dr., Jean Marie Basset Dr. basset@cpe.fr C2P2 Laboratoire de Chimie Organométallique de Surface, UMR 5265 CNRS—ESCPE Lyon, 43 Bd du 11 Novembre 1918, 69616 Villeurbanne Cedex, France, Fax: (+33) 472-431-795Search for more papers by this authorChristophe Copéret Dr., Christophe Copéret Dr. coperet@cpe.fr C2P2 Laboratoire de Chimie Organométallique de Surface, UMR 5265 CNRS—ESCPE Lyon, 43 Bd du 11 Novembre 1918, 69616 Villeurbanne Cedex, France, Fax: (+33) 472-431-795Search for more papers by this author Alain Salameh Dr., Alain Salameh Dr. C2P2 Laboratoire de Chimie Organométallique de Surface, UMR 5265 CNRS—ESCPE Lyon, 43 Bd du 11 Novembre 1918, 69616 Villeurbanne Cedex, France, Fax: (+33) 472-431-795Search for more papers by this authorJérôme Joubert Dr., Jérôme Joubert Dr. Laboratoire de Chimie, Institut de Chimie de Lyon, Ecole normale supérieure de Lyon, CNRS, 46 allée d'Italie, 69364 Lyon Cedex 07, France, Fax: (+33) 472-728-860Search for more papers by this authorAnne Baudouin, Anne Baudouin C2P2 Laboratoire de Chimie Organométallique de Surface, UMR 5265 CNRS—ESCPE Lyon, 43 Bd du 11 Novembre 1918, 69616 Villeurbanne Cedex, France, Fax: (+33) 472-431-795Search for more papers by this authorWayne Lukens Dr., Wayne Lukens Dr. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USASearch for more papers by this authorFrançoise Delbecq Dr., Françoise Delbecq Dr. Laboratoire de Chimie, Institut de Chimie de Lyon, Ecole normale supérieure de Lyon, CNRS, 46 allée d'Italie, 69364 Lyon Cedex 07, France, Fax: (+33) 472-728-860Search for more papers by this authorPhilippe Sautet Dr., Philippe Sautet Dr. philippe.sautet@ens-lyon.fr Laboratoire de Chimie, Institut de Chimie de Lyon, Ecole normale supérieure de Lyon, CNRS, 46 allée d'Italie, 69364 Lyon Cedex 07, France, Fax: (+33) 472-728-860Search for more papers by this authorJean Marie Basset Dr., Jean Marie Basset Dr. basset@cpe.fr C2P2 Laboratoire de Chimie Organométallique de Surface, UMR 5265 CNRS—ESCPE Lyon, 43 Bd du 11 Novembre 1918, 69616 Villeurbanne Cedex, France, Fax: (+33) 472-431-795Search for more papers by this authorChristophe Copéret Dr., Christophe Copéret Dr. coperet@cpe.fr C2P2 Laboratoire de Chimie Organométallique de Surface, UMR 5265 CNRS—ESCPE Lyon, 43 Bd du 11 Novembre 1918, 69616 Villeurbanne Cedex, France, Fax: (+33) 472-431-795Search for more papers by this author First published: 15 May 2007 https://doi.org/10.1002/ange.200700211Citations: 13 † A.S. is grateful to BASF for a graduate fellowship. We are all indebted to the BASF, CNRS, and ESCPE Lyon for financial support. This work was also sponsored in part by a grant to C.C. from the Agence Nationale pour la Recherche (ANR JC05 46372). We also thank Drs. V. Böhm, M. Röper, and D. Schneider for helpful discussions. Portions of this work were performed at the Lawrence Berkeley National Laboratory, which is operated by the US DOE under Contract No. DE-AC03-76SF00098, and at the Stanford Synchrotron Radiation Laboratory, a national user facility operated by Stanford University on behalf of the US DOE, Office of Basic Energy Sciences. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Aktive Minderheit: Die C-H-Aktivierung der Methylgruppe von CH3ReO3 an reaktiven Stellen einer Aluminiumoxidoberfläche liefert das aktive Zentrum von auf Aluminiumoxid aufgebrachtem CH3ReO3, einem hochaktiven Olefinmetathesekatalysator, während die Hauptkomponente, die durch Koordination von CH3ReO3 an dieselben Stellen entsteht, inaktiv ist (siehe Schema; Os sind die O-Atome der Aluminiumoxidoberfläche). Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2007/z700211_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume119, Issue21May 18, 2007Pages 3944-3947 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation