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Highly Enantioselective Insertion of Carbenoids into NH Bonds Catalyzed by Copper(I) Complexes of Binol Derivatives

2010; Wiley; Volume: 122; Issue: 28 Linguagem: Inglês

10.1002/ange.201001686

1521-3757

Zongrui Hou, Jun Wang, Peng He, Jing Wang, Bo Qin, Xiaohua Liu, Lili Lin, Xiaoming Feng,

Asymmetric Synthesis and Catalysis

Angewandte ChemieVolume 122, Issue 28 p. 4873-4876 Zuschrift Highly Enantioselective Insertion of Carbenoids into NH Bonds Catalyzed by Copper(I) Complexes of Binol Derivatives† Zongrui Hou, Zongrui Hou Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this authorJun Wang Dr., Jun Wang Dr. Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this authorPeng He, Peng He Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this authorJing Wang, Jing Wang Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this authorBo Qin Dr., Bo Qin Dr. Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this authorXiaohua Liu Dr., Xiaohua Liu Dr. Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this authorLili Lin Dr., Lili Lin Dr. Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this authorXiaoming Feng Prof. Dr., Xiaoming Feng Prof. Dr. xmfeng@scu.edu.cn Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this author Zongrui Hou, Zongrui Hou Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this authorJun Wang Dr., Jun Wang Dr. Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this authorPeng He, Peng He Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this authorJing Wang, Jing Wang Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this authorBo Qin Dr., Bo Qin Dr. Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this authorXiaohua Liu Dr., Xiaohua Liu Dr. Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this authorLili Lin Dr., Lili Lin Dr. Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this authorXiaoming Feng Prof. Dr., Xiaoming Feng Prof. Dr. xmfeng@scu.edu.cn Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University Chengdu 610064 (China), Fax: (+86) 28-8541-8249Search for more papers by this author First published: 21 June 2010 https://doi.org/10.1002/ange.201001686Citations: 23 † We acknowledge the National Natural Science Foundation of China (Nos. 20702033 and 20732003), the PCSIRT (No. IRT0846), and the National Basic Research Program of China (973 Program) (No. 2010CB833300) for financial support. We also thank the Sichuan University Analytical & Testing Center for NMR analysis and the State Key Laboratory of Biotherapy for HRMS analysis. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Sekundäre Amine können es auch! Die erfolgreiche katalytische asymmetrische Insertion von α-Diazoestern in die N-H-Bindung unterschiedlich substituierter Amine wird vorgestellt (siehe Schema; M.S.=Molekularsieb). Mit einer Vielzahl an Substraten wurden ausgezeichnete Enantioselektivitäten (bis 98 % ee) und hohe Ausbeuten (bis 99 %) unter milden Reaktionsbedingungen erhalten. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_201001686_sm_miscellaneous_information.pdf7.1 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume122, Issue28June 28, 2010Pages 4873-4876 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. 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