A Half‐Sandwich Ruthenium( II ) Complex Containing a Coordinatively Unsaturated 2,6‐Dimesitylphenyl Thiolate Ligand
2004; Wiley; Volume: 116; Issue: 17 Linguagem: Inglês
10.1002/ange.200353611
ISSN1521-3757
AutoresYasuhiro Ohki, H. Sadohara, Yuko Takikawa, Kazuyuki Tatsumi,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoAngewandte ChemieVolume 116, Issue 17 p. 2340-2343 Zuschrift A Half-Sandwich Ruthenium(II) Complex Containing a Coordinatively Unsaturated 2,6-Dimesitylphenyl Thiolate Ligand† Yasuhiro Ohki Dr., Yasuhiro Ohki Dr. Department of Chemistry, Graduate School of Science and Research Center for Meterials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan, Fax: (+81) 52-789-2943Search for more papers by this authorHitomi Sadohara, Hitomi Sadohara Department of Chemistry, Graduate School of Science and Research Center for Meterials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan, Fax: (+81) 52-789-2943Search for more papers by this authorYuko Takikawa, Yuko Takikawa Department of Chemistry, Graduate School of Science and Research Center for Meterials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan, Fax: (+81) 52-789-2943Search for more papers by this authorKazuyuki Tatsumi Prof. Dr., Kazuyuki Tatsumi Prof. Dr. [email protected] Department of Chemistry, Graduate School of Science and Research Center for Meterials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan, Fax: (+81) 52-789-2943Search for more papers by this author Yasuhiro Ohki Dr., Yasuhiro Ohki Dr. Department of Chemistry, Graduate School of Science and Research Center for Meterials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan, Fax: (+81) 52-789-2943Search for more papers by this authorHitomi Sadohara, Hitomi Sadohara Department of Chemistry, Graduate School of Science and Research Center for Meterials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan, Fax: (+81) 52-789-2943Search for more papers by this authorYuko Takikawa, Yuko Takikawa Department of Chemistry, Graduate School of Science and Research Center for Meterials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan, Fax: (+81) 52-789-2943Search for more papers by this authorKazuyuki Tatsumi Prof. Dr., Kazuyuki Tatsumi Prof. Dr. [email protected] Department of Chemistry, Graduate School of Science and Research Center for Meterials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan, Fax: (+81) 52-789-2943Search for more papers by this author First published: 16 April 2004 https://doi.org/10.1002/ange.200353611Citations: 9 † This research was financially supported by a Grant-in-Aid for Scientific Research (No. 14078211 and 15750047) from the Ministry of Education, Culture, Sports, Science, and Technology, Japan. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Der elektronenarme Rutheniumkomplex [Cp*Ru(SDmp)] (1; SDmp=2,6-Dimesitylphenylthiolat, Cp*=η5-C5Me5) stabilisiert sich durch die Koordination des Cipso-Atoms einer SDmp-Mesitylgruppe. Aus 1 können auf zweierlei Weise koordinativ ungesättigte Spezies generiert werden: Die Labilität von Cipso ermöglicht Reaktionen mit Liganden L, die reversible Dissoziation/Assoziation des SDmp-Liganden führt zur regioselektiven Cyclotrimerisierung substituierter Alkine (siehe Schema). Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2004/z53611_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 1aR. A. Andersen, K. Faegri, Jr.,J. C. Green, A. Haaland, M. F. Lappert, W.-P. Leung, K. Rypdal, Inorg. Chem. 1988, 27, 1782; 10.1021/ic00283a022 CASWeb of Science®Google Scholar 1bM. F. Lappert, D.-S. Liu, J. Organomet. Chem. 1995, 500, 203; 10.1016/0022-328X(95)00524-T CASWeb of Science®Google Scholar 1cC. C. Cummins, Prog. Inorg. Chem. 1998, 47, 685; 10.1002/9780470166482.ch7 CASWeb of Science®Google Scholar 1dS. Alvarez, Coord. Chem. Rev. 1999, 193–195, 13; 10.1016/S0010-8545(99)00085-5 CASWeb of Science®Google Scholar 1eI. P. Rothwell, Acc. Chem. 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