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Conformations of γ‐Aminobutyric Acid (GABA): The Role of the n→π* Interaction

2010; Wiley; Volume: 122; Issue: 48 Linguagem: Inglês

10.1002/ange.201002535

1521-3757

Susana Blanco, Juan C. López, Santiago Mata, José L. Alonso,

GABA and Rice Research

Angewandte ChemieVolume 122, Issue 48 p. 9373-9378 Zuschrift Conformations of γ-Aminobutyric Acid (GABA): The Role of the n→π* Interaction† Prof. Susana Blanco, Prof. Susana Blanco Grupo de Espectroscopía Molecular, Edificio Quifima, Area de Química Física, Campus Miguel Delibes, Universidad de Valladolid, 47011 Valladolid (Spain), Fax: (+34) 983-423-264 http://www.gem.uva.esSearch for more papers by this authorProf. Juan C. López, Corresponding Author Prof. Juan C. López jclopez@qf.uva.es Grupo de Espectroscopía Molecular, Edificio Quifima, Area de Química Física, Campus Miguel Delibes, Universidad de Valladolid, 47011 Valladolid (Spain), Fax: (+34) 983-423-264 http://www.gem.uva.esGrupo de Espectroscopía Molecular, Edificio Quifima, Area de Química Física, Campus Miguel Delibes, Universidad de Valladolid, 47011 Valladolid (Spain), Fax: (+34) 983-423-264 http://www.gem.uva.esSearch for more papers by this authorSantiago Mata, Santiago Mata Grupo de Espectroscopía Molecular, Edificio Quifima, Area de Química Física, Campus Miguel Delibes, Universidad de Valladolid, 47011 Valladolid (Spain), Fax: (+34) 983-423-264 http://www.gem.uva.esSearch for more papers by this authorProf. José L. Alonso, Prof. José L. Alonso Grupo de Espectroscopía Molecular, Edificio Quifima, Area de Química Física, Campus Miguel Delibes, Universidad de Valladolid, 47011 Valladolid (Spain), Fax: (+34) 983-423-264 http://www.gem.uva.esSearch for more papers by this author Prof. Susana Blanco, Prof. Susana Blanco Grupo de Espectroscopía Molecular, Edificio Quifima, Area de Química Física, Campus Miguel Delibes, Universidad de Valladolid, 47011 Valladolid (Spain), Fax: (+34) 983-423-264 http://www.gem.uva.esSearch for more papers by this authorProf. Juan C. López, Corresponding Author Prof. Juan C. López jclopez@qf.uva.es Grupo de Espectroscopía Molecular, Edificio Quifima, Area de Química Física, Campus Miguel Delibes, Universidad de Valladolid, 47011 Valladolid (Spain), Fax: (+34) 983-423-264 http://www.gem.uva.esGrupo de Espectroscopía Molecular, Edificio Quifima, Area de Química Física, Campus Miguel Delibes, Universidad de Valladolid, 47011 Valladolid (Spain), Fax: (+34) 983-423-264 http://www.gem.uva.esSearch for more papers by this authorSantiago Mata, Santiago Mata Grupo de Espectroscopía Molecular, Edificio Quifima, Area de Química Física, Campus Miguel Delibes, Universidad de Valladolid, 47011 Valladolid (Spain), Fax: (+34) 983-423-264 http://www.gem.uva.esSearch for more papers by this authorProf. José L. Alonso, Prof. José L. Alonso Grupo de Espectroscopía Molecular, Edificio Quifima, Area de Química Física, Campus Miguel Delibes, Universidad de Valladolid, 47011 Valladolid (Spain), Fax: (+34) 983-423-264 http://www.gem.uva.esSearch for more papers by this author First published: 06 October 2010 https://doi.org/10.1002/ange.201002535Citations: 18 † This research was supported by the Ministerio de Educación y Ciencia (MEC, grants CTQ2006-05981/BQU and Consolider Ingenio 2010 CSD2009-00038) and the Junta de Castilla y León (grant VA070A08). Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Die neun Konformere des Neurotransmitters γ-Aminobuttersäure (GABA), die in der Gasphase identifiziert wurden, dienen als Grundlage bei der Zuweisung einer Form für GABA. Eine n→π*-Wechselwirkung entlang der Bürgi-Dunitz-Trajektorie der nucleophilen Addition scheint für die Stabilisierung zweier Konformere von Bedeutung zu sein (gG1 und gG3 im Bild). Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_201002535_sm_miscellaneous_information.pdf1,018.9 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume122, Issue48November 22, 2010Pages 9373-9378 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation