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One‐Step Catalytic Asymmetric Synthesis of Configurationally Stable Tröger Bases

2011; Wiley; Volume: 123; Issue: 16 Linguagem: Inglês

10.1002/ange.201100134

1521-3757

Ankit Sharma, Laure Guénée, Jean‐Valère Naubron, Jérôme Lacour,

Cyclopropane Reaction Mechanisms

Angewandte ChemieVolume 123, Issue 16 p. 3761-3764 Zuschrift One-Step Catalytic Asymmetric Synthesis of Configurationally Stable Tröger Bases† Ankit Sharma, Ankit Sharma Department of Organic Chemistry, University of Geneva quai Ernest Ansermet 30, 1211 Genève 4 (Switzerland), Fax: (+41) 22-379-3215 http://www.unige.ch/sciences/chiorg/lacour/Search for more papers by this authorDr. Laure Guénée, Dr. Laure Guénée Laboratory of Crystallography, University of Geneva quai Ernest Ansermet 24, 1211 Genève 4 (Switzerland)Search for more papers by this authorDr. Jean-Valère Naubron, Dr. Jean-Valère Naubron Spectropole—Campus Saint Jérôme, 13397 Marseille Cedex 20 (France)Search for more papers by this authorProf. Jérôme Lacour, Corresponding Author Prof. Jérôme Lacour jerome.lacour@unige.ch Department of Organic Chemistry, University of Geneva quai Ernest Ansermet 30, 1211 Genève 4 (Switzerland), Fax: (+41) 22-379-3215 http://www.unige.ch/sciences/chiorg/lacour/Department of Organic Chemistry, University of Geneva quai Ernest Ansermet 30, 1211 Genève 4 (Switzerland), Fax: (+41) 22-379-3215 http://www.unige.ch/sciences/chiorg/lacour/Search for more papers by this author Ankit Sharma, Ankit Sharma Department of Organic Chemistry, University of Geneva quai Ernest Ansermet 30, 1211 Genève 4 (Switzerland), Fax: (+41) 22-379-3215 http://www.unige.ch/sciences/chiorg/lacour/Search for more papers by this authorDr. Laure Guénée, Dr. Laure Guénée Laboratory of Crystallography, University of Geneva quai Ernest Ansermet 24, 1211 Genève 4 (Switzerland)Search for more papers by this authorDr. Jean-Valère Naubron, Dr. Jean-Valère Naubron Spectropole—Campus Saint Jérôme, 13397 Marseille Cedex 20 (France)Search for more papers by this authorProf. Jérôme Lacour, Corresponding Author Prof. Jérôme Lacour jerome.lacour@unige.ch Department of Organic Chemistry, University of Geneva quai Ernest Ansermet 30, 1211 Genève 4 (Switzerland), Fax: (+41) 22-379-3215 http://www.unige.ch/sciences/chiorg/lacour/Department of Organic Chemistry, University of Geneva quai Ernest Ansermet 30, 1211 Genève 4 (Switzerland), Fax: (+41) 22-379-3215 http://www.unige.ch/sciences/chiorg/lacour/Search for more papers by this author First published: 18 March 2011 https://doi.org/10.1002/ange.201100134Citations: 16 † We thank Dr. D. Jeannerat and A. Pinto for NMR measurements, the University of Geneva, and the Swiss National Science Foundation for financial support. We also acknowledge the contributions of the Sciences Mass Spectrometry (SMS) platform at the Faculty of Sciences (University of Geneva), and the CRCMM and the Spectropole at the University of Aix-Marseille for computer time and use of the VCD facility, respectively. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Brückenbauarbeiten: Konfigurationsstabile ethanoverbrückte Tröger-Basen werden in einer Stufe durch eine Rhodium(II)-katalysierte Reaktion von methanoverbrückten Tröger-Basen mit Diazoestern erhalten (siehe Schema). Der Prozess ist enantiospezifisch, diastereoselektiv (ein neues quartäres Kohlenstoffzentrum wird eingeführt) und regioselektiv sowie allgemein anwendbar. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_201100134_sm_miscellaneous_information.pdf2.3 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume123, Issue16April 11, 2011Pages 3761-3764 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation