Artigo Revisado por pares

Metal–Organic Nanoporous Structures with Anisotropic Photoluminescence and Magnetic Properties and Their Use as Sensors

2008; Wiley; Volume: 120; Issue: 6 Linguagem: Inglês

10.1002/ange.200704702

ISSN

1521-3757

Autores

Bogdan Harbuzaru, Avelino Corma, Fernando Rey, Pedro Atienzar, J.L. Jordá, Hermenegildo Garcı́a, Duarte Ananias, Luís D. Carlos, João Rocha,

Tópico(s)

Magnetism in coordination complexes

Resumo

Angewandte ChemieVolume 120, Issue 6 p. 1096-1099 Zuschrift Metal–Organic Nanoporous Structures with Anisotropic Photoluminescence and Magnetic Properties and Their Use as Sensors† Bogdan V. Harbuzaru Dr., Bogdan V. Harbuzaru Dr. Instituto de Tecnología Química, (UPV-CSIC), Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain, Fax: (+34) 96-387-7809Search for more papers by this authorAvelino Corma Prof. Dr., Avelino Corma Prof. Dr. [email protected] Instituto de Tecnología Química, (UPV-CSIC), Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain, Fax: (+34) 96-387-7809Search for more papers by this authorFernando Rey Dr., Fernando Rey Dr. Instituto de Tecnología Química, (UPV-CSIC), Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain, Fax: (+34) 96-387-7809Search for more papers by this authorPedro Atienzar Dr., Pedro Atienzar Dr. Instituto de Tecnología Química, (UPV-CSIC), Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain, Fax: (+34) 96-387-7809Search for more papers by this authorJose L. Jordá Dr., Jose L. Jordá Dr. Instituto de Tecnología Química, (UPV-CSIC), Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain, Fax: (+34) 96-387-7809Search for more papers by this authorHermenegildo García Prof. Dr., Hermenegildo García Prof. Dr. Instituto de Tecnología Química, (UPV-CSIC), Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain, Fax: (+34) 96-387-7809Search for more papers by this authorDuarte Ananias Dr., Duarte Ananias Dr. Departments of Chemistry and Physics, CICECO, University of Aveiro, 3810-193 Aveiro, PortugalSearch for more papers by this authorLuis D. Carlos Prof. Dr., Luis D. Carlos Prof. Dr. Departments of Chemistry and Physics, CICECO, University of Aveiro, 3810-193 Aveiro, PortugalSearch for more papers by this authorJoão Rocha Prof. Dr., João Rocha Prof. Dr. Departments of Chemistry and Physics, CICECO, University of Aveiro, 3810-193 Aveiro, PortugalSearch for more papers by this author Bogdan V. Harbuzaru Dr., Bogdan V. Harbuzaru Dr. Instituto de Tecnología Química, (UPV-CSIC), Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain, Fax: (+34) 96-387-7809Search for more papers by this authorAvelino Corma Prof. Dr., Avelino Corma Prof. Dr. [email protected] Instituto de Tecnología Química, (UPV-CSIC), Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain, Fax: (+34) 96-387-7809Search for more papers by this authorFernando Rey Dr., Fernando Rey Dr. Instituto de Tecnología Química, (UPV-CSIC), Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain, Fax: (+34) 96-387-7809Search for more papers by this authorPedro Atienzar Dr., Pedro Atienzar Dr. Instituto de Tecnología Química, (UPV-CSIC), Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain, Fax: (+34) 96-387-7809Search for more papers by this authorJose L. Jordá Dr., Jose L. Jordá Dr. Instituto de Tecnología Química, (UPV-CSIC), Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain, Fax: (+34) 96-387-7809Search for more papers by this authorHermenegildo García Prof. Dr., Hermenegildo García Prof. Dr. Instituto de Tecnología Química, (UPV-CSIC), Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain, Fax: (+34) 96-387-7809Search for more papers by this authorDuarte Ananias Dr., Duarte Ananias Dr. Departments of Chemistry and Physics, CICECO, University of Aveiro, 3810-193 Aveiro, PortugalSearch for more papers by this authorLuis D. Carlos Prof. Dr., Luis D. Carlos Prof. Dr. Departments of Chemistry and Physics, CICECO, University of Aveiro, 3810-193 Aveiro, PortugalSearch for more papers by this authorJoão Rocha Prof. Dr., João Rocha Prof. Dr. Departments of Chemistry and Physics, CICECO, University of Aveiro, 3810-193 Aveiro, PortugalSearch for more papers by this author First published: 21 January 2008 https://doi.org/10.1002/ange.200704702Citations: 69 † The authors thank Spanish CICYT for financial support (MAT2006-08039, MAT2006-14274-C02-01), and Beamline BM-16 at ESRF in Grenoble for beam time allocation. Also, the authors would like to thank the European Network of Excellence FAME. D.A., L.D.C., and J.R. thank FTC and FEDER. J.L.J. thanks I3 program of CSIC (200680|180) for partial financial support. We also thank F. Delgado-Trujillo for helpful discussions. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Bunte Lichter: Poröse metall-organische Netzwerke sind wichtige Materialien mit Anwendungsmöglichkeiten als Sensoren. Neuartige nanoporöse Seltenerdmetall-Materialien haben die höchsten Emissionsquantenausbeuten unter allen Eu3+-Festkörpern mit organischen Liganden und zeigen außerdem magnetische Eigenschaften. Das Bild zeigt [Gd,Eu]- und [Tb]-Materialien unter UV-Licht und dem Einfluss eines Magneten. Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2008/z704702_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1C. C. Freyhardt, M. Tsapatsis, R. F. Lobo, K. J. Balkus, M. E. Davis, Nature 1996, 381, 295–298. 10.1038/381295a0 CASWeb of Science®Google Scholar 2A. Corma, M. J. Díaz-Cabanas, J. L. Jorda, C. Martínez, M. Moliner, Nature 2006, 443, 842–845. 10.1038/nature05238 CASPubMedWeb of Science®Google Scholar 3M. H. Kostova, D. Ananias, F. A. Almeida Paz, A. Ferreira, J. Rocha, L. D. Carlos, J. Phys. Chem. B 2007, 111, 3576–3582. 10.1021/jp068559u CASPubMedWeb of Science®Google Scholar 4B. D. Chandler, D. T. Cramb, G. K. H. Shimizu, J. Am. Chem. 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