Brønsted Acid Mediated Heterogeneous Addition Reaction of 1,3‐Dicarbonyl Compounds to Alkenes and Alcohols
2006; Wiley; Volume: 118; Issue: 16 Linguagem: Inglês
10.1002/ange.200504609
ISSN1521-3757
AutoresKen Motokura, Noriaki Fujita, Kohsuke Mori, Tomoo Mizugaki, Kohki Ebitani, Kiyotomi Kaneda,
Tópico(s)Asymmetric Hydrogenation and Catalysis
ResumoAngewandte ChemieVolume 118, Issue 16 p. 2667-2671 Zuschrift Brønsted Acid Mediated Heterogeneous Addition Reaction of 1,3-Dicarbonyl Compounds to Alkenes and Alcohols† Ken Motokura Dr., Ken Motokura Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorNoriaki Fujita, Noriaki Fujita Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorKohsuke Mori Dr., Kohsuke Mori Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorTomoo Mizugaki Dr., Tomoo Mizugaki Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorKohki Ebitani Dr., Kohki Ebitani Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorKiyotomi Kaneda Prof. Dr., Kiyotomi Kaneda Prof. Dr. [email protected] Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this author Ken Motokura Dr., Ken Motokura Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorNoriaki Fujita, Noriaki Fujita Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorKohsuke Mori Dr., Kohsuke Mori Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorTomoo Mizugaki Dr., Tomoo Mizugaki Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorKohki Ebitani Dr., Kohki Ebitani Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorKiyotomi Kaneda Prof. Dr., Kiyotomi Kaneda Prof. Dr. [email protected] Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this author First published: 04 April 2006 https://doi.org/10.1002/ange.200504609Citations: 29 † This investigation was supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science, and Technology of Japan (16206078). We thank the Center of Excellence (21COE; "Creation of Integrated Ecochemistry" program, Osaka University). We are also grateful to Prof. Dr. S. Namba (Teikyo University) for catalyst preparation and Dr. K. Mori, Dr. Y. Senga, and Dr. S. Yamakita (Bel Japan) for TPD measurement. K.M. thanks the JSPS for a Research Fellowship for Young Scientists. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Die hohe Säurestärke eines durch Protonenaustausch aktivierten Montmorillonit-Katalysators (H-Mont) wurde für die nucleophile Addition von 1,3-Dicarbonylverbindungen an einfache Alkene genutzt (siehe Schema). Auch Benzylierungen und Allylierungen von 1,3-Dicarbonylverbindungen mit Alkoholen sowie nucleophile Additionen von Carbonsäuren an Alkene verlaufen mit H-Mont glatt. Der Katalysator konnte ohne Aktivitätsverlust siebenmal wiederverwendet werden. Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2006/z504609_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 1aB. M. 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