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High‐Molecular‐Weight Poly(vinylphosphonate)s by Single‐Component Living Polymerization Initiated by Rare‐Earth‐Metal Complexes

2010; Wiley; Volume: 122; Issue: 20 Linguagem: Inglês

10.1002/ange.201000804

1521-3757

Uwe B. Seemann, Joachim Dengler, Bernhard Rieger,

Synthetic Organic Chemistry Methods

Angewandte ChemieVolume 122, Issue 20 p. 3567-3569 Zuschrift High-Molecular-Weight Poly(vinylphosphonate)s by Single-Component Living Polymerization Initiated by Rare-Earth-Metal Complexes† Uwe B. Seemann, Uwe B. Seemann Technische Universität München, WACKER-Lehrstuhl für Makromolekulare Chemie, Lichtenbergstrasse 4, 85747 Garching bei München (Germany), Fax: (+49) 89-289-13562 http://www.makro.ch.tum.de/Search for more papers by this authorJoachim E. Dengler, Joachim E. Dengler Technische Universität München, WACKER-Lehrstuhl für Makromolekulare Chemie, Lichtenbergstrasse 4, 85747 Garching bei München (Germany), Fax: (+49) 89-289-13562 http://www.makro.ch.tum.de/Search for more papers by this authorBernhard Rieger Prof., Bernhard Rieger Prof. rieger@tum.de Technische Universität München, WACKER-Lehrstuhl für Makromolekulare Chemie, Lichtenbergstrasse 4, 85747 Garching bei München (Germany), Fax: (+49) 89-289-13562 http://www.makro.ch.tum.de/Search for more papers by this author Uwe B. Seemann, Uwe B. Seemann Technische Universität München, WACKER-Lehrstuhl für Makromolekulare Chemie, Lichtenbergstrasse 4, 85747 Garching bei München (Germany), Fax: (+49) 89-289-13562 http://www.makro.ch.tum.de/Search for more papers by this authorJoachim E. Dengler, Joachim E. Dengler Technische Universität München, WACKER-Lehrstuhl für Makromolekulare Chemie, Lichtenbergstrasse 4, 85747 Garching bei München (Germany), Fax: (+49) 89-289-13562 http://www.makro.ch.tum.de/Search for more papers by this authorBernhard Rieger Prof., Bernhard Rieger Prof. rieger@tum.de Technische Universität München, WACKER-Lehrstuhl für Makromolekulare Chemie, Lichtenbergstrasse 4, 85747 Garching bei München (Germany), Fax: (+49) 89-289-13562 http://www.makro.ch.tum.de/Search for more papers by this author First published: 27 April 2010 https://doi.org/10.1002/ange.201000804Citations: 20 † We thank Dr. Carly Anderson and Dr. Sergei Vagin for their support with preparing the manuscript. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Übertragbar: Auf einem Gruppentransferpolymerisations(GTP)-Mechanismus beruht die lebende Polymerisation von Diethylvinylphosphonat zu Homo- und Copolymeren mit hohen Molekulargewichten in Gegenwart einfacher Seltenerdmetall-Komplexe (siehe Schema). Dieser Mechanismus, der dem etablierten Mechanismus für polare Monomere wie Acrylate entspricht, öffnet einen neuen Zugang zu phosphorhaltigen Polymeren. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_201000804_sm_miscellaneous_information.pdf1.2 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume122, Issue20May 3, 2010Pages 3567-3569 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation