Synthesis of Secondary Enamides by Ruthenium‐Catalyzed Selective Addition of Amides to Terminal Alkynes
2008; Wiley; Volume: 120; Issue: 44 Linguagem: Alemão
10.1002/ange.200803068
ISSN1521-3757
AutoresLukas J. Gooßen, Kifah S. M. Salih, Mathieu Blanchot,
Tópico(s)Catalytic Alkyne Reactions
ResumoAngewandte ChemieVolume 120, Issue 44 p. 8620-8623 Zuschrift Synthesis of Secondary Enamides by Ruthenium-Catalyzed Selective Addition of Amides to Terminal Alkynes† Lukas J. Gooßen Prof. Dr., Lukas J. Gooßen Prof. Dr. goossen@chemie.uni-kl.de FB Chemie—Organische Chemie, TU Kaiserslautern, Erwin-Schrödinger-Strasse Geb. 54, 67663 Kaiserslautern (Germany), Fax: (+49) 631-205-3921 http://www.chemie.uni-kl.de/goossenSearch for more papers by this authorKifah S. M. Salih, Kifah S. M. Salih FB Chemie—Organische Chemie, TU Kaiserslautern, Erwin-Schrödinger-Strasse Geb. 54, 67663 Kaiserslautern (Germany), Fax: (+49) 631-205-3921 http://www.chemie.uni-kl.de/goossenSearch for more papers by this authorMathieu Blanchot, Mathieu Blanchot FB Chemie—Organische Chemie, TU Kaiserslautern, Erwin-Schrödinger-Strasse Geb. 54, 67663 Kaiserslautern (Germany), Fax: (+49) 631-205-3921 http://www.chemie.uni-kl.de/goossenSearch for more papers by this author Lukas J. Gooßen Prof. Dr., Lukas J. Gooßen Prof. Dr. goossen@chemie.uni-kl.de FB Chemie—Organische Chemie, TU Kaiserslautern, Erwin-Schrödinger-Strasse Geb. 54, 67663 Kaiserslautern (Germany), Fax: (+49) 631-205-3921 http://www.chemie.uni-kl.de/goossenSearch for more papers by this authorKifah S. M. Salih, Kifah S. M. Salih FB Chemie—Organische Chemie, TU Kaiserslautern, Erwin-Schrödinger-Strasse Geb. 54, 67663 Kaiserslautern (Germany), Fax: (+49) 631-205-3921 http://www.chemie.uni-kl.de/goossenSearch for more papers by this authorMathieu Blanchot, Mathieu Blanchot FB Chemie—Organische Chemie, TU Kaiserslautern, Erwin-Schrödinger-Strasse Geb. 54, 67663 Kaiserslautern (Germany), Fax: (+49) 631-205-3921 http://www.chemie.uni-kl.de/goossenSearch for more papers by this author First published: 15 October 2008 https://doi.org/10.1002/ange.200803068Citations: 29 † We thank the DFG and Umicore AG for financial support. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Enamide leicht gemacht: Ein Katalysator, der in situ aus Bis(2-methallyl)(cycloocta-1,5-dien)ruthenium(II), 1,4-Bis(dicyclohexylphosphanyl)butan und Ytterbiumtriflat erhalten wird, vermittelt effizient die Addition primärer Amide an terminale Alkine, die selektiv zu den Z-Anti-Markownikow-Enamiden führt. Die E-Isomere sind zugänglich, indem man die Hydroamidierung mit einer In-situ-Doppelbindungsisomerisierung kombiniert. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_200803068_sm_miscellaneous_information.pdf664.5 KB miscellaneous information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume120, Issue44October 20, 2008Pages 8620-8623 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation
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