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Synthesis and Properties of 4,5,6‐Triphospha[3]radialene

2012; Wiley; Volume: 124; Issue: 14 Linguagem: Inglês

10.1002/ange.201200374

1521-3757

H. Miyake, Takahiro Sasamori, Norihiro Tokitoh,

Coordination Chemistry and Organometallics

Angewandte ChemieVolume 124, Issue 14 p. 3514-3517 Zuschrift Synthesis and Properties of 4,5,6-Triphospha[3]radialene† Dr. Hideaki Miyake, Dr. Hideaki Miyake Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan) http://boc.kuicr.kyoto-u.ac.jp/www/index-e.htmlSearch for more papers by this authorProf. Dr. Takahiro Sasamori, Corresponding Author Prof. Dr. Takahiro Sasamori sasamori@boc.kuicr.kyoto-u.ac.jp Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan) http://boc.kuicr.kyoto-u.ac.jp/www/index-e.htmlInstitute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan) http://boc.kuicr.kyoto-u.ac.jp/www/index-e.htmlSearch for more papers by this authorProf. Dr. Norihiro Tokitoh, Corresponding Author Prof. Dr. Norihiro Tokitoh tokitoh@boc.kuicr.kyoto-u.ac.jp Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan) http://boc.kuicr.kyoto-u.ac.jp/www/index-e.htmlInstitute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan) http://boc.kuicr.kyoto-u.ac.jp/www/index-e.htmlSearch for more papers by this author Dr. Hideaki Miyake, Dr. Hideaki Miyake Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan) http://boc.kuicr.kyoto-u.ac.jp/www/index-e.htmlSearch for more papers by this authorProf. Dr. Takahiro Sasamori, Corresponding Author Prof. Dr. Takahiro Sasamori sasamori@boc.kuicr.kyoto-u.ac.jp Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan) http://boc.kuicr.kyoto-u.ac.jp/www/index-e.htmlInstitute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan) http://boc.kuicr.kyoto-u.ac.jp/www/index-e.htmlSearch for more papers by this authorProf. Dr. Norihiro Tokitoh, Corresponding Author Prof. Dr. Norihiro Tokitoh tokitoh@boc.kuicr.kyoto-u.ac.jp Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan) http://boc.kuicr.kyoto-u.ac.jp/www/index-e.htmlInstitute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan) http://boc.kuicr.kyoto-u.ac.jp/www/index-e.htmlSearch for more papers by this author First published: 22 February 2012 https://doi.org/10.1002/ange.201200374Citations: 13 † This work was partially supported by Grants-in-Aid for Scientific Research (B) (No. 22350017), Young Scientist (A) (No. 23685010), and the Global COE Program B09 from the Ministry of Education, Culture, Sports, Science and Technology (Japan). JSPS Fellows were supported by grant number 23 3938 from the Japan Society for the Promotion of Science. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract [3]Radialene: Die synthetisierte Titelverbindung (siehe Bild) kann trotz ihrer [3]Radialen-Einheit mit PC-Bindungen unter Umgebungsbedingungen problemlos an der Luft gehandhabt werden und zeigt eine rotverschobene Absorption sowie ein hohes Elektronenakzeptorvermögen. Der Ursprung dieser ungewöhnlichen elektronischen Eigenschaften ist eine Synergie zwischen dem [3]Radialen-Gerüst und der Phosphorsubstitution. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_201200374_sm_miscellaneous_information.pdf371.8 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume124, Issue14April 2, 2012Pages 3514-3517 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation