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Capture of Periodate in a {W 18 O 54 } Cluster Cage Yielding a Catalytically Active Polyoxometalate [H 3 W 18 O 56 (IO 6 )] 6− Embedded with High‐Valent Iodine

2008; Wiley; Volume: 120; Issue: 23 Linguagem: Inglês

10.1002/ange.200800041

1521-3757

De‐Liang Long, Yu‐Fei Song, ELIZABETH WILSON, Paul Kögerler, Si‐Xuan Guo, Alan M. Bond, Justin S. J. Hargreaves, Leroy Cronin,

Nanocluster Synthesis and Applications

Angewandte ChemieVolume 120, Issue 23 p. 4456-4459 Zuschrift Capture of Periodate in a {W18O54} Cluster Cage Yielding a Catalytically Active Polyoxometalate [H3W18O56(IO6)]6− Embedded with High-Valent Iodine† De-Liang Long Dr., De-Liang Long Dr. longd@chem.gla.ac.uk WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland, UK, Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/leeSearch for more papers by this authorYu-Fei Song Dr., Yu-Fei Song Dr. WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland, UK, Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/leeSearch for more papers by this authorElizabeth F. Wilson, Elizabeth F. Wilson WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland, UK, Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/leeSearch for more papers by this authorPaul Kögerler Prof. Dr., Paul Kögerler Prof. Dr. Institut für Anorganische Chemie, RWTH Aachen, 52074 Aachen, GermanySearch for more papers by this authorSi-Xuan Guo Dr., Si-Xuan Guo Dr. School of Chemistry, Monash University, Clayton, Victoria 3800, AustraliaSearch for more papers by this authorAlan M. Bond Prof., Alan M. Bond Prof. School of Chemistry, Monash University, Clayton, Victoria 3800, AustraliaSearch for more papers by this authorJustin S. J. Hargreaves Dr., Justin S. J. Hargreaves Dr. WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland, UK, Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/leeSearch for more papers by this authorLeroy Cronin Prof. Dr., Leroy Cronin Prof. Dr. L.Cronin@chem.gla.ac.uk WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland, UK, Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/leeSearch for more papers by this author De-Liang Long Dr., De-Liang Long Dr. longd@chem.gla.ac.uk WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland, UK, Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/leeSearch for more papers by this authorYu-Fei Song Dr., Yu-Fei Song Dr. WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland, UK, Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/leeSearch for more papers by this authorElizabeth F. Wilson, Elizabeth F. Wilson WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland, UK, Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/leeSearch for more papers by this authorPaul Kögerler Prof. Dr., Paul Kögerler Prof. Dr. Institut für Anorganische Chemie, RWTH Aachen, 52074 Aachen, GermanySearch for more papers by this authorSi-Xuan Guo Dr., Si-Xuan Guo Dr. School of Chemistry, Monash University, Clayton, Victoria 3800, AustraliaSearch for more papers by this authorAlan M. Bond Prof., Alan M. Bond Prof. School of Chemistry, Monash University, Clayton, Victoria 3800, AustraliaSearch for more papers by this authorJustin S. J. Hargreaves Dr., Justin S. J. Hargreaves Dr. WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland, UK, Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/leeSearch for more papers by this authorLeroy Cronin Prof. Dr., Leroy Cronin Prof. Dr. L.Cronin@chem.gla.ac.uk WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow G12 8QQ, Scotland, UK, Fax: (+44) 141-330-4888 http://www.chem.gla.ac.uk/staff/leeSearch for more papers by this author First published: 16 May 2008 https://doi.org/10.1002/ange.200800041Citations: 26 † We thank the EPSRC, WestCHEM and the University of Glasgow for supporting this work. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Periodat im Zentrum: Ein Wolframperiodatcluster der Form β*-[H3W18O56(IO6)]6−, in dem Periodat in einen {W18O54}-Käfig eingeschlossen ist, konnte als erstes [HnW18O56(XO6)]m−-Heteropolyoxowolframat kristallographisch charakterisiert werden. Massenspektrometrische, elektrochemische und Katalysestudien sowie DFT-Rechnungen offenbaren die ungewöhnlichen physikalischen Eigenschaften der Clusterstruktur, die auch in Lösung intakt bleibt. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2008/z800041_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume120, Issue23May 26, 2008Pages 4456-4459 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation