Artigo Revisado por pares

Controlling Rigidity and Planarity in Conjugated Polymers: Poly(3,4‐ethylenedithioselenophene)

2009; Wiley; Volume: 121; Issue: 30 Linguagem: Inglês

10.1002/ange.200901231

ISSN

1521-3757

Autores

Y.H. Wijsboom, Asit Patra, Sanjio S. Zade, Y. Sheynin, Mao Li, Linda J. W. Shimon, Michael Bendikov,

Tópico(s)

Perovskite Materials and Applications

Resumo

Angewandte ChemieVolume 121, Issue 30 p. 5551-5555 Zuschrift Controlling Rigidity and Planarity in Conjugated Polymers: Poly(3,4-ethylenedithioselenophene)† Yair H. Wijsboom, Yair H. Wijsboom Department of Organic Chemistry, Weizmann Institute of Science, Rehovot 76100 (Israel), Fax: (+972) 8934-4142 http://www.weizmann.ac.il/oc/bendikov/Search for more papers by this authorAsit Patra Dr., Asit Patra Dr. Department of Organic Chemistry, Weizmann Institute of Science, Rehovot 76100 (Israel), Fax: (+972) 8934-4142 http://www.weizmann.ac.il/oc/bendikov/Search for more papers by this authorSanjio S. Zade Dr., Sanjio S. Zade Dr. Department of Organic Chemistry, Weizmann Institute of Science, Rehovot 76100 (Israel), Fax: (+972) 8934-4142 http://www.weizmann.ac.il/oc/bendikov/ Current address: School of Chemistry, Indian Institute of Science, Education and Research, Kolkata-700106 (India)Search for more papers by this authorYana Sheynin Dr., Yana Sheynin Dr. Department of Organic Chemistry, Weizmann Institute of Science, Rehovot 76100 (Israel), Fax: (+972) 8934-4142 http://www.weizmann.ac.il/oc/bendikov/Search for more papers by this authorMao Li Dr., Mao Li Dr. Department of Organic Chemistry, Weizmann Institute of Science, Rehovot 76100 (Israel), Fax: (+972) 8934-4142 http://www.weizmann.ac.il/oc/bendikov/Search for more papers by this authorLinda J. W. Shimon Dr., Linda J. W. Shimon Dr. Chemical Research Support Unit, Weizmann Institute of Science (Israel)Search for more papers by this authorMichael Bendikov Dr., Michael Bendikov Dr. michael.bendikov@weizmann.ac.il Department of Organic Chemistry, Weizmann Institute of Science, Rehovot 76100 (Israel), Fax: (+972) 8934-4142 http://www.weizmann.ac.il/oc/bendikov/Search for more papers by this author Yair H. Wijsboom, Yair H. Wijsboom Department of Organic Chemistry, Weizmann Institute of Science, Rehovot 76100 (Israel), Fax: (+972) 8934-4142 http://www.weizmann.ac.il/oc/bendikov/Search for more papers by this authorAsit Patra Dr., Asit Patra Dr. Department of Organic Chemistry, Weizmann Institute of Science, Rehovot 76100 (Israel), Fax: (+972) 8934-4142 http://www.weizmann.ac.il/oc/bendikov/Search for more papers by this authorSanjio S. Zade Dr., Sanjio S. Zade Dr. Department of Organic Chemistry, Weizmann Institute of Science, Rehovot 76100 (Israel), Fax: (+972) 8934-4142 http://www.weizmann.ac.il/oc/bendikov/ Current address: School of Chemistry, Indian Institute of Science, Education and Research, Kolkata-700106 (India)Search for more papers by this authorYana Sheynin Dr., Yana Sheynin Dr. Department of Organic Chemistry, Weizmann Institute of Science, Rehovot 76100 (Israel), Fax: (+972) 8934-4142 http://www.weizmann.ac.il/oc/bendikov/Search for more papers by this authorMao Li Dr., Mao Li Dr. Department of Organic Chemistry, Weizmann Institute of Science, Rehovot 76100 (Israel), Fax: (+972) 8934-4142 http://www.weizmann.ac.il/oc/bendikov/Search for more papers by this authorLinda J. W. Shimon Dr., Linda J. W. Shimon Dr. Chemical Research Support Unit, Weizmann Institute of Science (Israel)Search for more papers by this authorMichael Bendikov Dr., Michael Bendikov Dr. michael.bendikov@weizmann.ac.il Department of Organic Chemistry, Weizmann Institute of Science, Rehovot 76100 (Israel), Fax: (+972) 8934-4142 http://www.weizmann.ac.il/oc/bendikov/Search for more papers by this author First published: 08 July 2009 https://doi.org/10.1002/ange.200901231Citations: 23 † We thank Prof. Dmitrii F. Perepichka (McGill University) for helpful discussions. We thank the MINERVA Foundation and the Israel Science Foundation for financial support. M.B. is the incumbent of the Recanati career development chair, a member ad personam of the Lise Meitner-Minerva Center for Computational Quantum Chemistry, and acknowledges DuPont for a Young Professor′s Award. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Platt wie eine Flunder: Schon kleine Substituenten können eine deutliche Verdrillung im Rückgrat von konjugierten Polymeren erzeugen, die das Ausmaß der Konjugation verringert und zu größeren Bandlücken führt. Oligo- und Polyselenophene sind starrer als ihre Thiophenanaloga und behalten ihre Planarität und ihre kleine Bandlücke auch bei Substitution bei. Das Bild zeigt zwei Selenophendimere; Se pink, S gelb. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_200901231_sm_miscellaneous_information.pdf644.8 KB miscellaneous information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume121, Issue30July 13, 2009Pages 5551-5555 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation

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