Cis ‐Specific Topochemical Polymerization: Alternating Copolymerization of 7,7,8,8‐Tetrakis(methoxycarbonyl)quinodimethane with 7,7,8,8‐Tetracyanoquinodimethane in the Solid State
2011; Wiley; Volume: 123; Issue: 10 Linguagem: Inglês
10.1002/ange.201006928
ISSN1521-3757
AutoresTakahito Itoh, Tatsuya Suzuki, Takahiro Uno, Masataka Kubo, Norimitsu Tohnai, Mikiji Miyata,
Tópico(s)Luminescence and Fluorescent Materials
ResumoAngewandte ChemieVolume 123, Issue 10 p. 2301-2304 Zuschrift Cis-Specific Topochemical Polymerization: Alternating Copolymerization of 7,7,8,8-Tetrakis(methoxycarbonyl)quinodimethane with 7,7,8,8-Tetracyanoquinodimethane in the Solid State† Prof. Dr. Takahito Itoh, Corresponding Author Prof. Dr. Takahito Itoh [email protected] Division of Chemistry for Materials, Graduate School of Engineering, Mie University, 1577 Kurima Machiya-cho, Tsu-shi, Mie 514-8507 (Japan), Fax: (+81) 59-231-9410Division of Chemistry for Materials, Graduate School of Engineering, Mie University, 1577 Kurima Machiya-cho, Tsu-shi, Mie 514-8507 (Japan), Fax: (+81) 59-231-9410Search for more papers by this authorTatsuya Suzuki, Tatsuya Suzuki Division of Chemistry for Materials, Graduate School of Engineering, Mie University, 1577 Kurima Machiya-cho, Tsu-shi, Mie 514-8507 (Japan), Fax: (+81) 59-231-9410Search for more papers by this authorDr. Takahiro Uno, Dr. Takahiro Uno Division of Chemistry for Materials, Graduate School of Engineering, Mie University, 1577 Kurima Machiya-cho, Tsu-shi, Mie 514-8507 (Japan), Fax: (+81) 59-231-9410Search for more papers by this authorProf. Dr. Masataka Kubo, Prof. Dr. Masataka Kubo Graduate School of Regional Innovation Studies, Mie University, 1577 Kurima Machiya-cho, Tsu-shi, Mie 514-8507 (Japan)Search for more papers by this authorDr. Norimitsu Tohnai, Dr. Norimitsu Tohnai Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan)Search for more papers by this authorProf. Dr. Mikiji Miyata, Prof. Dr. Mikiji Miyata Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan)Search for more papers by this author Prof. Dr. Takahito Itoh, Corresponding Author Prof. Dr. Takahito Itoh [email protected] Division of Chemistry for Materials, Graduate School of Engineering, Mie University, 1577 Kurima Machiya-cho, Tsu-shi, Mie 514-8507 (Japan), Fax: (+81) 59-231-9410Division of Chemistry for Materials, Graduate School of Engineering, Mie University, 1577 Kurima Machiya-cho, Tsu-shi, Mie 514-8507 (Japan), Fax: (+81) 59-231-9410Search for more papers by this authorTatsuya Suzuki, Tatsuya Suzuki Division of Chemistry for Materials, Graduate School of Engineering, Mie University, 1577 Kurima Machiya-cho, Tsu-shi, Mie 514-8507 (Japan), Fax: (+81) 59-231-9410Search for more papers by this authorDr. Takahiro Uno, Dr. Takahiro Uno Division of Chemistry for Materials, Graduate School of Engineering, Mie University, 1577 Kurima Machiya-cho, Tsu-shi, Mie 514-8507 (Japan), Fax: (+81) 59-231-9410Search for more papers by this authorProf. Dr. Masataka Kubo, Prof. Dr. Masataka Kubo Graduate School of Regional Innovation Studies, Mie University, 1577 Kurima Machiya-cho, Tsu-shi, Mie 514-8507 (Japan)Search for more papers by this authorDr. Norimitsu Tohnai, Dr. Norimitsu Tohnai Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan)Search for more papers by this authorProf. Dr. Mikiji Miyata, Prof. Dr. Mikiji Miyata Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan)Search for more papers by this author First published: 31 January 2011 https://doi.org/10.1002/ange.201006928Citations: 17 † This research was supported financially by a Grant-in-Aid for Scientific Research (No. 22550110) from the Ministry of Education, Culture, Sports, Science and Technology (Japan). Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Einkristall bleibt Einkristall: Ein kristalliner Charge-Transfer-Komplex aus den Titelverbindungen geht unter UV-Bestrahlung oder beim Erhitzen eine radikalische topochemische Polymerisation ein. Diese cis-spezifische Copolymerisation der substituierten Chinodimethane im Festkörper erfordert eine Verkippung der alternierenden Monomere im Cokristall (siehe Bild). References 1 1aG. Wegner, Z. Naturforsch. 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Crystal-structure data for the 1⋅2 cocrystal: platelet, C14H10N2O4, Mr=270.24, 0.10×0.10×0.10 mm3, triclinic, space group (No. 2), a=7.7988(3), b=8.1224(3), c=11.8862(4) Å, α=76.603(3), β=79.720(3), γ=61.862(3)°, V=643.78(4) Å3, Z=2, ρcalcd=1.394 g cm−3, T=123.1 K, μ(CuKα)=0.880 mm−1, 2θmax=136°, 6875 reflections collected, 1849 unique (Rint=0.067) reflections. The final R1 and wR2 values were 0.0485 [I>2.0σ(I)] and 0.1420 (all data), respectively. Crystal structure data for poly(1⋅2): platelet, C14H10N2O4, Mr=270.24, 0.10×0.10×0.10 mm3, triclinic, space group (No. 2), a=7.0153(9), b=7.8433(9), c=12.1307(14) Å, α=80.101(5), β=86.502(6), γ=70.580(6)°, V=620.11(13) Å3, Z=2, ρcalcd=1.447 g cm−3, T=123.1 K, μ(CuKα)=0.914 mm−1, 2θmax=136°, 11 245 reflections collected, 3054 unique (Rint=0.279) reflections. The final R1 and wR2 values were 0.1377 [I>2.0σ(I)] and 0.4058 (all data), respectively. Google Scholar 9A. A. Bright, A. F. Garito, A. 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