Highly Stereoselective Cyclopropanation of α,β‐Unsaturated Carbonyl Compounds with Methyl (Diazoacetoxy)acetate Catalyzed by a Chiral Ruthenium(II) Complex
2013; Wiley; Volume: 125; Issue: 22 Linguagem: Inglês
10.1002/ange.201300468
ISSN1521-3757
AutoresSoda Chanthamath, Suguru Takaki, Kazutaka Shibatomi, Seiji Iwasa,
Tópico(s)Asymmetric Hydrogenation and Catalysis
ResumoAngewandte ChemieVolume 125, Issue 22 p. 5930-5933 Zuschrift Highly Stereoselective Cyclopropanation of α,β-Unsaturated Carbonyl Compounds with Methyl (Diazoacetoxy)acetate Catalyzed by a Chiral Ruthenium(II) Complex† Soda Chanthamath, Soda Chanthamath Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Tempaku-cho, Toyohashi, Aichi 441-8580 (Japan)Search for more papers by this authorSuguru Takaki, Suguru Takaki Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Tempaku-cho, Toyohashi, Aichi 441-8580 (Japan)Search for more papers by this authorProf. Dr. Kazutaka Shibatomi, Prof. Dr. Kazutaka Shibatomi Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Tempaku-cho, Toyohashi, Aichi 441-8580 (Japan)Search for more papers by this authorProf. Dr. Seiji Iwasa, Corresponding Author Prof. Dr. Seiji Iwasa [email protected] Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Tempaku-cho, Toyohashi, Aichi 441-8580 (Japan)Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Tempaku-cho, Toyohashi, Aichi 441-8580 (Japan)Search for more papers by this author Soda Chanthamath, Soda Chanthamath Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Tempaku-cho, Toyohashi, Aichi 441-8580 (Japan)Search for more papers by this authorSuguru Takaki, Suguru Takaki Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Tempaku-cho, Toyohashi, Aichi 441-8580 (Japan)Search for more papers by this authorProf. Dr. Kazutaka Shibatomi, Prof. Dr. Kazutaka Shibatomi Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Tempaku-cho, Toyohashi, Aichi 441-8580 (Japan)Search for more papers by this authorProf. Dr. Seiji Iwasa, Corresponding Author Prof. Dr. Seiji Iwasa [email protected] Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Tempaku-cho, Toyohashi, Aichi 441-8580 (Japan)Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Tempaku-cho, Toyohashi, Aichi 441-8580 (Japan)Search for more papers by this author First published: 16 April 2013 https://doi.org/10.1002/ange.201300468Citations: 10 † This work was supported by a Grant-in-Aid for Scientific Research (C) (No. 20550137) from the Japan Society for the Promotion of Science. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Spannende Dreiecke: Die Titelreaktion liefert Bicarbonylcyclopropane, aus denen mit hohen Ausbeuten und Stereoselektivitäten nützliche Intermediate zugänglich sind. Das System wurde außerdem für die enantioselektive Totalsynthese von Spirocyclopropanoxindol genutzt, einem nichtnucleosiden Inhibitor der reversen Transcriptase von HIV-1. Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. 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