Electrocatalytic O 2 Reduction at a Bio-inspired Mononuclear Copper Phenolato Complex Immobilized on a Carbon Nanotube Electrode
2016; Wiley; Volume: 128; Issue: 7 Linguagem: Inglês
10.1002/ange.201509593
ISSN1521-3757
AutoresSolène Gentil, Doti Serre, Christian Philouze, Michael Holzinger, Fabrice Thomas, Alan Le Goff,
Tópico(s)Electrocatalysts for Energy Conversion
ResumoAngewandte ChemieVolume 128, Issue 7 p. 2563-2566 Zuschrift Electrocatalytic O2 Reduction at a Bio-inspired Mononuclear Copper Phenolato Complex Immobilized on a Carbon Nanotube Electrode Solène Gentil, Solène Gentil Département de Chimie Moléculaire, UMR CNRS 5250, Univ. Grenoble Alpes, 570 rue de la Chimie, B. P. 53, 38041 Grenoble cedex 9, France These authors contributed equally to this work.Search for more papers by this authorDoti Serre, Doti Serre Département de Chimie Moléculaire, UMR CNRS 5250, Univ. Grenoble Alpes, 570 rue de la Chimie, B. P. 53, 38041 Grenoble cedex 9, France These authors contributed equally to this work.Search for more papers by this authorDr. Christian Philouze, Dr. Christian Philouze Département de Chimie Moléculaire, UMR CNRS 5250, Univ. Grenoble Alpes, 570 rue de la Chimie, B. P. 53, 38041 Grenoble cedex 9, FranceSearch for more papers by this authorDr. Michael Holzinger, Dr. Michael Holzinger Département de Chimie Moléculaire, UMR CNRS 5250, Univ. Grenoble Alpes, 570 rue de la Chimie, B. P. 53, 38041 Grenoble cedex 9, FranceSearch for more papers by this authorProf. Fabrice Thomas, Corresponding Author Prof. Fabrice Thomas [email protected] Département de Chimie Moléculaire, UMR CNRS 5250, Univ. Grenoble Alpes, 570 rue de la Chimie, B. P. 53, 38041 Grenoble cedex 9, FranceSearch for more papers by this authorDr. Alan Le Goff, Corresponding Author Dr. Alan Le Goff [email protected] orcid.org/0000-0002-6765-5859 Département de Chimie Moléculaire, UMR CNRS 5250, Univ. Grenoble Alpes, 570 rue de la Chimie, B. P. 53, 38041 Grenoble cedex 9, FranceSearch for more papers by this author Solène Gentil, Solène Gentil Département de Chimie Moléculaire, UMR CNRS 5250, Univ. Grenoble Alpes, 570 rue de la Chimie, B. P. 53, 38041 Grenoble cedex 9, France These authors contributed equally to this work.Search for more papers by this authorDoti Serre, Doti Serre Département de Chimie Moléculaire, UMR CNRS 5250, Univ. Grenoble Alpes, 570 rue de la Chimie, B. P. 53, 38041 Grenoble cedex 9, France These authors contributed equally to this work.Search for more papers by this authorDr. Christian Philouze, Dr. Christian Philouze Département de Chimie Moléculaire, UMR CNRS 5250, Univ. Grenoble Alpes, 570 rue de la Chimie, B. P. 53, 38041 Grenoble cedex 9, FranceSearch for more papers by this authorDr. Michael Holzinger, Dr. Michael Holzinger Département de Chimie Moléculaire, UMR CNRS 5250, Univ. Grenoble Alpes, 570 rue de la Chimie, B. P. 53, 38041 Grenoble cedex 9, FranceSearch for more papers by this authorProf. Fabrice Thomas, Corresponding Author Prof. Fabrice Thomas [email protected] Département de Chimie Moléculaire, UMR CNRS 5250, Univ. Grenoble Alpes, 570 rue de la Chimie, B. P. 53, 38041 Grenoble cedex 9, FranceSearch for more papers by this authorDr. Alan Le Goff, Corresponding Author Dr. Alan Le Goff [email protected] orcid.org/0000-0002-6765-5859 Département de Chimie Moléculaire, UMR CNRS 5250, Univ. Grenoble Alpes, 570 rue de la Chimie, B. P. 53, 38041 Grenoble cedex 9, FranceSearch for more papers by this author First published: 08 January 2016 https://doi.org/10.1002/ange.201509593Citations: 15 Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract An original copper-phenolate complex, mimicking the active center of galactose oxidase, featuring a pyrene group was synthesized. Supramolecular pi-stacking allows its efficient and soft immobilization at the surface of a Multi-Walled Carbon Nanotube (MWCNT) electrode. This MWCNT-supported galactose oxidase model exhibits a 4 H+/4 e− electrocatalytic activity towards oxygen reduction at a redox potential of 0.60 V vs. RHE at pH 5. Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description ange201509593-sup-0001-misc_information.pdf878.8 KB Supplementary Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1E. A. Lewis, W. B. Tolman, Chem. Rev. 2004, 104, 1047–1076. 10.1021/cr020633r CASPubMedWeb of Science®Google Scholar 2E. I. Solomon, D. E. Heppner, E. M. Johnston, J. W. Ginsbach, J. Cirera, M. Qayyum, M. T. Kieber-Emmons, C. H. Kjaergaard, R. G. Hadt, L. Tian, Chem. Rev. 2014, 114, 3659–3853. 10.1021/cr400327t CASPubMedWeb of Science®Google Scholar 3J. W. Whittaker, Chem. Rev. 2003, 103, 2347–2364. 10.1021/cr020425z CASPubMedWeb of Science®Google Scholar 4D. Das, Y.-M. Lee, K. Ohkubo, W. Nam, K. D. Karlin, S. Fukuzumi, J. Am. Chem. Soc. 2013, 135, 2825–2834. 10.1021/ja312523u CASPubMedWeb of Science®Google Scholar 5S. Kakuda, R. L. Peterson, K. 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