Carbon–Nitrogen Chains
2006; American Chemical Society; Linguagem: Holandês
10.1002/9783527627226.ch10
ISSN1520-5835
Autores Tópico(s)Luminescence and Fluorescent Materials
ResumoChapter 10 Carbon–Nitrogen Chains Hans-Georg Elias, Hans-Georg EliasSearch for more papers by this author Hans-Georg Elias, Hans-Georg EliasSearch for more papers by this author Hans-Georg Elias, Hans-Georg EliasSearch for more papers by this author Book Author(s):Hans-Georg Elias, Hans-Georg EliasSearch for more papers by this author First published: 07 December 2006 https://doi.org/10.1002/9783527627226.ch10 AboutPDFPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShareShare a linkShare onEmailFacebookTwitterLinkedInRedditWechat Summary This chapter discusses carbon-nitrogen chains such as cyanide polymers, imine, amine polymers, polyamides, polyureas, amino resins, polycyanates and polyazines. The simplest carbon-nitrogen polymers are, in principle, obtained from monomers with polymerizable cyano groups, -C = N. The cyano group is isomeric to the isocyanide or isonitrile group, -NC, which was formerly called carbamyl. The systematic nomenclature would use poly(iminoethylene) instead of poly(ethylene imine) and poly((1-methylamino)ethylene) instead of poly(N-methyl vinyl amine). Polyamides are polymers with amide groups -NH-CO- in the main chain. PA 6.6 and PA 6 are the classical polyamides. Since DuPont and IG Farben exchanged patents and divided markets, PA 6.6 still dominates in the US and England whereas PA 6 is the main polyamide in Germany and Japan. Polyureas contain the characteristic ureylene group -NH-CO-NH-. As derivatives of urea, H2N-CO-NH2, they are known as polyureylenes and, since urea is the monoamide of the hypothetical carbamic acid, H2N-CO-OH, also as polycarbamides. 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