Nickel(II) Phosphate VSB-5: A Magnetic Nanoporous Hydrogenation Catalyst with 24-Ring Tunnels
2001; Wiley; Volume: 113; Issue: 15 Linguagem: Alemão
10.1002/1521-3757(20010803)113
ISSN1521-3757
AutoresNathalie Guillou, Qiuming Gao, Paul M. Forster, Jong‐San Chang, Marc Noguès, Sang‐Eon Park, Gérard Férey, Anthony K. Cheetham,
Tópico(s)Asymmetric Hydrogenation and Catalysis
ResumoAngewandte ChemieVolume 113, Issue 15 p. 2913-2916 Zuschrift Nickel(II) Phosphate VSB-5: A Magnetic Nanoporous Hydrogenation Catalyst with 24-Ring Tunnels Nathalie Guillou Dr., Nathalie Guillou Dr. Institut Lavoisier, UMR CNRS C 8637 Université de Versailles Saint-Quentin-en-Yvelines 45 avenue des Etats-Unis, 78035 Versailles Cedex (France) Fax: (+33) 1-39-25-43-58Search for more papers by this authorQiuming Gao Dr., Qiuming Gao Dr. Institut Lavoisier, UMR CNRS C 8637 Université de Versailles Saint-Quentin-en-Yvelines 45 avenue des Etats-Unis, 78035 Versailles Cedex (France) Fax: (+33) 1-39-25-43-58Search for more papers by this authorPaul M. Forster, Paul M. Forster Materials Research Laboratory University of California Santa Barbara, CA 93106 (USA) Fax: (+1) 805-893-8797Search for more papers by this authorJong-San Chang Dr., Jong-San Chang Dr. Materials Research Laboratory University of California Santa Barbara, CA 93106 (USA) Fax: (+1) 805-893-8797Search for more papers by this authorMarc Noguès Dr., Marc Noguès Dr. Institut Lavoisier, UMR CNRS C 8637 Université de Versailles Saint-Quentin-en-Yvelines 45 avenue des Etats-Unis, 78035 Versailles Cedex (France) Fax: (+33) 1-39-25-43-58Search for more papers by this authorSang-Eon Park Dr., Sang-Eon Park Dr. [email protected] Catalysis Center for Molecular Engineering Korea Research Institute of Chemical Technology (KRICT) P. O. Box 107, Yusung, Taejon 305-606 (Korea) Fax: (+82) 42-860-7676Search for more papers by this authorGérard Férey Prof., Gérard Férey Prof. [email protected] Institut Lavoisier, UMR CNRS C 8637 Université de Versailles Saint-Quentin-en-Yvelines 45 avenue des Etats-Unis, 78035 Versailles Cedex (France) Fax: (+33) 1-39-25-43-58Search for more papers by this authorAnthony K. Cheetham Prof., Anthony K. Cheetham Prof. [email protected] Institut Lavoisier, UMR CNRS C 8637 Université de Versailles Saint-Quentin-en-Yvelines 45 avenue des Etats-Unis, 78035 Versailles Cedex (France) Fax: (+33) 1-39-25-43-58Search for more papers by this author Nathalie Guillou Dr., Nathalie Guillou Dr. Institut Lavoisier, UMR CNRS C 8637 Université de Versailles Saint-Quentin-en-Yvelines 45 avenue des Etats-Unis, 78035 Versailles Cedex (France) Fax: (+33) 1-39-25-43-58Search for more papers by this authorQiuming Gao Dr., Qiuming Gao Dr. Institut Lavoisier, UMR CNRS C 8637 Université de Versailles Saint-Quentin-en-Yvelines 45 avenue des Etats-Unis, 78035 Versailles Cedex (France) Fax: (+33) 1-39-25-43-58Search for more papers by this authorPaul M. Forster, Paul M. Forster Materials Research Laboratory University of California Santa Barbara, CA 93106 (USA) Fax: (+1) 805-893-8797Search for more papers by this authorJong-San Chang Dr., Jong-San Chang Dr. Materials Research Laboratory University of California Santa Barbara, CA 93106 (USA) Fax: (+1) 805-893-8797Search for more papers by this authorMarc Noguès Dr., Marc Noguès Dr. Institut Lavoisier, UMR CNRS C 8637 Université de Versailles Saint-Quentin-en-Yvelines 45 avenue des Etats-Unis, 78035 Versailles Cedex (France) Fax: (+33) 1-39-25-43-58Search for more papers by this authorSang-Eon Park Dr., Sang-Eon Park Dr. [email protected] Catalysis Center for Molecular Engineering Korea Research Institute of Chemical Technology (KRICT) P. O. Box 107, Yusung, Taejon 305-606 (Korea) Fax: (+82) 42-860-7676Search for more papers by this authorGérard Férey Prof., Gérard Férey Prof. [email protected] Institut Lavoisier, UMR CNRS C 8637 Université de Versailles Saint-Quentin-en-Yvelines 45 avenue des Etats-Unis, 78035 Versailles Cedex (France) Fax: (+33) 1-39-25-43-58Search for more papers by this authorAnthony K. Cheetham Prof., Anthony K. Cheetham Prof. [email protected] Institut Lavoisier, UMR CNRS C 8637 Université de Versailles Saint-Quentin-en-Yvelines 45 avenue des Etats-Unis, 78035 Versailles Cedex (France) Fax: (+33) 1-39-25-43-58Search for more papers by this author First published: 03 August 2001 https://doi.org/10.1002/1521-3757(20010803)113:15 3.0.CO;2-PCitations: 59 A.K.C. thanks the Fondation de l'Ecole Normale Supérieure and the Région de l'Ile de France for a Chaire Internationale de Recherche, Blaise Pascal. We also thank the CNRS for financial support and for providing a Poste Rouge for Q.G. and a PICS to the two groups for cooperation. The authors are indebted to D. S. Kim for his support with pore size analysis. We thank the Korean Ministry of Science and Technology (Key Research Program, KK-0005-F0) for supporting this work, and the Korea Science and Engineering Foundation (KOSEF) Fellowship for J.S.C. is gratefully acknowledged. J.S.C. was partially supported by the U.S. Department of Energy under grant DE-FG03-96ER14672. P.M.F. was supported by the National Science Foundation under the MRSEC Program (NSF-DMR-96-32716). Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Nanoporosität und hohe thermische Stabilität, dazu antiferromagnetische Ordnung und gute katalytische Eigenschaften bei Hydrierungen sind vier wesentliche Eigenschaften des großporigen (24MR), zeolithischen Nickel(II)-phosphats VSB-5 (Ni20[(OH)12(H2O)6][(HPO4)8(PO4)4]⋅12 H2O), das unter alkalischen Bedingungen durch Hydrothermalsynthese erhalten wurde (siehe Struktur; grün: NiO6-Oktaeder, rot: PO4-Tetraeder). References 1 A. Corma, Chem. 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To avoid preferred orientation effects, the synthesis was carried out under stirring conditions, keeping the same experimental conditions with the same molar ratio and filling rate. The resulting powder was then loaded in the sample holder. The powder diffraction pattern was scanned over an angular range of 4–120° (2θ). The counting times were 27 s per step to 59.98° (2θ) and 54 s per step from 60.00° (2θ) to the end of the scan (to improve the counting statistics of the high-angle region). The full pattern was then scaled to the lower counting time. An accurate determination of the peak positions and relative intensities was carried out by using the software package DIFFRACT-AT. Google Scholar 13 A. Boultif, D. Louër, J. Appl. Crystallogr. 1991, 24, 987–993. 10.1107/S0021889891006441 CASWeb of Science®Google Scholar 14 A. Altomare, M. C. Burla, G. Cascarano, C. Giacovazzo, A. Guagliardi, A. G. G. Moliterni, G. Polidori, J. Appl. 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Google Scholar 19 The selective hydrogenation of 1,3-butadiene to butenes was carried out in a continuous fixed-bed reactor made of quartz at atmospheric pressure. Before catalytic measurement, the catalyst was reduced with 5 % hydrogen in helium at 350 °C for 4–24 h. The reaction was carried out while introducing mixture of 1,3-butadiene (99.0 %) and pure hydrogen under helium. The effluent stream from the reactor was analyzed by an on-line gas chromatograph (HP 5890 Series II) fitted with a capillary column (J&W Alumina) and a flame-ionization detector. Google Scholar 20 H. Arnold, F. Doebert, J. Gaube in Handbook of Heterogeneous Catalysis, Vol. 5 ( ), VCH, Weinheim, 1997, pp. 2165–2186. Google Scholar 21 E. Iglesia, D. G. Barton, J. A. Biscardi, M. J. L. Gines, S. L. Soled, Catal. Today 1997, 38, 339–360. 10.1016/S0920-5861(97)81503-7 Web of Science®Google Scholar 22 Decomposition of MBOH (>99 %, Aldrich) was carried out in a plug-flow glass reactor with an internal diameter of 10 mm. The MBOH was placed in a vaporizer in which a helium flow was saturated with the alcohol vapor at 298 K and then the MBOH/helium mixture was fed into the reactor. The catalytic activity of VSB-5 was examined after the calcination of the fresh sample at 623 K for 4 h in air. Reaction products were analyzed by an on-line gas chromatograph (Hewlett-Packard model 5890II) fitted with a capillary column (J&W DB-WAX) and a flame-ionization detector. Google Scholar Citing Literature Volume113, Issue15August 3, 2001Pages 2913-2916 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. 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