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BIBTEX RIS

Mg 2 Ru 2 Cl 10 O·16H 2 O

2006; Wiley; Volume: 63; Issue: 1 Linguagem: Inglês

10.1107/s0108270106050839

ISSN

1600-5759

Autores

Sihem Boufas, Hocine Mérazig, Lamia Bendjeddou, Georges Dénès, Adel Beghidja, Anna Moliterni,

Tópico(s)

Inorganic Chemistry and Materials

Resumo

Mg2Ru2Cl10O.16H2O {dimagnesium mu-oxo-bis[pentachlororuthenate(IV)] hexadecahydrate} crystallizes in the monoclinic system (space group P2(1)/c). The structure consists of layers of [Ru2Cl10O]4- anions, [Mg(H2O)6]2+ cations and water molecules stacked along the a axis. Only the O atom bonded to Ru occupies the 2a site with -1 symmetry. All the other atoms occupy general 4e sites. The crystal structure is stabilized by O-H...O and O-H...Cl interactions.

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