Multinuclear Copper Triethanolamine Complexes as Selective Catalysts for the Peroxidative Oxidation of Alkanes under Mild Conditions
2005; Wiley; Volume: 117; Issue: 28 Linguagem: Inglês
10.1002/ange.200500585
ISSN1521-3757
AutoresAlexander M. Kirillov, Maximilian N. Kopylovich, Marina V. Kirillova, Matti Haukka, M. Fátima C. Guedes da Silva, Armando J. L. Pombeiro,
Tópico(s)Porphyrin and Phthalocyanine Chemistry
ResumoAngewandte ChemieVolume 117, Issue 28 p. 4419-4423 Zuschrift Multinuclear Copper Triethanolamine Complexes as Selective Catalysts for the Peroxidative Oxidation of Alkanes under Mild Conditions† Alexander M. Kirillov, Alexander M. Kirillov Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001, Lisbon, Portugal, Fax: (+351) 21-846-4455Search for more papers by this authorMaximilian N. Kopylovich Dr., Maximilian N. Kopylovich Dr. Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001, Lisbon, Portugal, Fax: (+351) 21-846-4455Search for more papers by this authorMarina V. Kirillova, Marina V. Kirillova Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001, Lisbon, Portugal, Fax: (+351) 21-846-4455Search for more papers by this authorMatti Haukka Dr., Matti Haukka Dr. Department of Chemistry, University of Joensuu, P.O. Box 111, FIN-80101, Joensuu, FinlandSearch for more papers by this authorM. Fátima C. Guedes da Silva Dr., M. Fátima C. Guedes da Silva Dr. Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001, Lisbon, Portugal, Fax: (+351) 21-846-4455Search for more papers by this authorArmando J. L. Pombeiro Prof., Armando J. L. Pombeiro Prof. [email protected] Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001, Lisbon, Portugal, Fax: (+351) 21-846-4455Search for more papers by this author Alexander M. Kirillov, Alexander M. Kirillov Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001, Lisbon, Portugal, Fax: (+351) 21-846-4455Search for more papers by this authorMaximilian N. Kopylovich Dr., Maximilian N. Kopylovich Dr. Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001, Lisbon, Portugal, Fax: (+351) 21-846-4455Search for more papers by this authorMarina V. Kirillova, Marina V. Kirillova Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001, Lisbon, Portugal, Fax: (+351) 21-846-4455Search for more papers by this authorMatti Haukka Dr., Matti Haukka Dr. Department of Chemistry, University of Joensuu, P.O. Box 111, FIN-80101, Joensuu, FinlandSearch for more papers by this authorM. Fátima C. Guedes da Silva Dr., M. Fátima C. Guedes da Silva Dr. Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001, Lisbon, Portugal, Fax: (+351) 21-846-4455Search for more papers by this authorArmando J. L. Pombeiro Prof., Armando J. L. Pombeiro Prof. [email protected] Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001, Lisbon, Portugal, Fax: (+351) 21-846-4455Search for more papers by this author First published: 04 July 2005 https://doi.org/10.1002/ange.200500585Citations: 35 † This work has been partially supported by the Fundação para a Ciência e a Tecnologia and its POCTI programme (FEDER funded) (project POCTI/QUI/43415/2001), Portugal, and by a Human Resources and Mobility Marie-Curie Research Training Network (AQUACHEM project, CMTN-CT-2003-503864). Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Nur ein paar Kupferlinge: Einfach zu erzeugende zwei-, drei-, vier- und mehrkernige Kupfer-Triethanolamin-Komplexe sind selektive und wirksame Katalysatoren für die Oxidation von Alkanen zu Alkoholen mit Wasserstoffperoxid unter milden Bedingungen (siehe Bild). Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2005/z500585_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 1aS. Itoh in Comprehensive Coordination Chemistry, Vol. 8 (Eds.: ), 2nd ed., Elsevier, Dordrecht, 2003, chap. 8.15, pp. 369–393; Web of Science®Google Scholar 1bD. H. 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A 2003, 247, 269. 10.1016/S0926-860X(03)00125-X CASWeb of Science®Google Scholar 10X-ray crystal-structure analyses: 1: C13H21CuNO6, Mr=350.85, monoclinic, P21/n:b2, crystal size 0.66×0.43×0.25 mm3, a=7.556(5), b=26.922(5), c=8.014(5) Å, α=90.046(5), β=111.070(5), γ=89.980(5)°, V=1521.2(14) Å3, T=293(2) K, Z=4, ρcalcd=1.523 Mg m−3, μ=1.461 mm−1, F(000)=724, max/min transm.=0.7115/0.4456, Θ=1.51–25.08°; 5318 reflections observed, 2680 unique (Rint=0.1244); R1=0.0583, wR2=0.1467 (I>2σ(I)), R1=0.0908, wR2=0.1663 (all data), largest difference peak and hole: 1.137/−0.803 e Å−3. 2: C52H90Cu6N4O34, Mr=1696.52, monoclinic, C2/c, crystal size 0.14×0.09×0.05 mm3, a=20.1793(4), b=11.2602(2), c=16.1429(2) Å, α=γ=90, β=116.5880(10)°, V=3280.13(10) Å3, T=100(2) K, Z=2, ρcalcd=1.718 Mg m−3, μ=2.007 mm−1, F(000)=1752, max/min transm.=0.34702/0.30557, Θ=3.11–26.36°, 20 924 reflections observed, 3341 unique (Rint=0.0383); R1=0.0338, wR2=0.0895 (I>2σ(I)), R1=0.0380, wR2=0.0927 (all data), largest difference peak and hole: 2.021/−0.869 e Å−3. 3: C24H52B6Cu4F8N4O17, Mr=1139.72, triclinic, P̄1, crystal size 0.32×0.27×0.25 mm3, a=12.1081(3), b=18.4078(4), c=18.6603(5) Å, α=98.928(2), β=100.5170(10), γ=101.041(2)°, V=3934.82(17) Å3, T=100(2) K, Z=4, ρcalcd=1.924 Mg m−3, μ=2.248 mm−1, F(000)=2312, max/min transm.=0.6001/0.5305, Θ=3.06–26.00°; 47 993 reflections observed, 15 132 unique (Rint=0.0384); R1=0.0495, wR2=0.1203 (I>2σ(I)), R1=0.0726, wR2=0.1376 (all data), largest difference peak and hole: 1.929/−0.761 e Å−3. 4: C10H18CuNO6 Mr=311.79, triclinic, P̄1, crystal size 0.26×0.18×0.11 mm3, a=7.4983(8), b=7.9730(6), c=10.8652(13) Å, α=84.071(8), β=89.669(8), γ=70.382(6)°, V=608.30(11) Å3, T=100(2) K, Z=2, ρcalcd=1.702 Mg m−3, μ=1.815 mm−1, F(000)=324, max/min transm.=0.8212/0.6448, Θ=2.73–27.50°; 6244 reflections observed, 2748 unique (Rint=0.0174); R1=0.0251, wR2=0.0576 [I>2σ(I)], R1=0.0315, wR2=0.0601 (all data), largest difference peak and hole: 0.468/−0.354 e Å−3. CCDC 259925 (1), 259926 (2), 259927 (3), and 259928 (4) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif. Google Scholar 11G. B. Shul'pin, Y. N. Kozlov, G. V. Nizova, G. Süss-Fink, S. Stanislas, A. Kitaygorodskiy, V. S. Kulikova, J. Chem. Soc. Perkin Trans. 2 2001, 1351. 10.1039/b101442k CASWeb of Science®Google Scholar 12L. M. Slaughter, J. P. Collman, T. A. Eberspacher, J. I. Brauman, Inorg. Chem. 2004, 43, 5198. 10.1021/ic049922j CASPubMedWeb of Science®Google Scholar 13R. W. Cruse, S. Kaderli, C. J. Meyer, A. D. Zuberbühler, K. D. Karlin, J. Am. Chem. Soc. 1988, 110, 5020. 10.1021/ja00223a020 CASWeb of Science®Google Scholar Citing Literature Volume117, Issue28July 11, 2005Pages 4419-4423 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. 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