Portal de Periódicos da CAPES

A Combined NRVS and DFT Study of Fe IV O Model Complexes: A Diagnostic Method for the Elucidation of Non‐Heme Iron Enzyme Intermediates

2008; Wiley; Volume: 120; Issue: 47 Linguagem: Inglês

10.1002/ange.200803740

1521-3757

Caleb B. Bell, Shaun D. Wong, Yuming Xiao, Eric J. Klinker, Adam L. Tenderholt, Matt C. Smith, Jan‐Uwe Rohde, Lawrence Que, Stephen P. Cramer, Edward I. Solomon,

Hemoglobin structure and function

Angewandte ChemieVolume 120, Issue 47 p. 9211-9214 Zuschrift A Combined NRVS and DFT Study of FeIVO Model Complexes: A Diagnostic Method for the Elucidation of Non-Heme Iron Enzyme Intermediates† Caleb B. Bell III, Caleb B. Bell III Department of Chemistry, Stanford University, Stanford, CA 94305-5080 (USA), Fax: (+1) 650-725-0259Search for more papers by this authorShaun D. Wong, Shaun D. Wong Department of Chemistry, Stanford University, Stanford, CA 94305-5080 (USA), Fax: (+1) 650-725-0259Search for more papers by this authorYuming Xiao Dr., Yuming Xiao Dr. Department of Applied Science, University of California, Davis Physical Biosciences Division, Lawrence Berkeley National Laboratory (USA)Search for more papers by this authorEric J. Klinker Dr., Eric J. Klinker Dr. Department of Chemistry, University of Minnesota (USA)Search for more papers by this authorAdam L. Tenderholt, Adam L. Tenderholt Department of Chemistry, Stanford University, Stanford, CA 94305-5080 (USA), Fax: (+1) 650-725-0259Search for more papers by this authorMatt C. Smith Dr., Matt C. Smith Dr. Department of Applied Science, University of California, Davis Physical Biosciences Division, Lawrence Berkeley National Laboratory (USA)Search for more papers by this authorJan-Uwe Rohde Dr., Jan-Uwe Rohde Dr. Department of Chemistry, University of Minnesota (USA)Search for more papers by this authorLawrence Que Jr. Prof., Lawrence Que Jr. Prof. Department of Chemistry, University of Minnesota (USA)Search for more papers by this authorStephen P. Cramer Prof., Stephen P. Cramer Prof. Department of Applied Science, University of California, Davis Physical Biosciences Division, Lawrence Berkeley National Laboratory (USA)Search for more papers by this authorEdward I. Solomon Prof., Edward I. Solomon Prof. Edward.Solomon@stanford.edu Department of Chemistry, Stanford University, Stanford, CA 94305-5080 (USA), Fax: (+1) 650-725-0259Search for more papers by this author Caleb B. Bell III, Caleb B. Bell III Department of Chemistry, Stanford University, Stanford, CA 94305-5080 (USA), Fax: (+1) 650-725-0259Search for more papers by this authorShaun D. Wong, Shaun D. Wong Department of Chemistry, Stanford University, Stanford, CA 94305-5080 (USA), Fax: (+1) 650-725-0259Search for more papers by this authorYuming Xiao Dr., Yuming Xiao Dr. Department of Applied Science, University of California, Davis Physical Biosciences Division, Lawrence Berkeley National Laboratory (USA)Search for more papers by this authorEric J. Klinker Dr., Eric J. Klinker Dr. Department of Chemistry, University of Minnesota (USA)Search for more papers by this authorAdam L. Tenderholt, Adam L. Tenderholt Department of Chemistry, Stanford University, Stanford, CA 94305-5080 (USA), Fax: (+1) 650-725-0259Search for more papers by this authorMatt C. Smith Dr., Matt C. Smith Dr. Department of Applied Science, University of California, Davis Physical Biosciences Division, Lawrence Berkeley National Laboratory (USA)Search for more papers by this authorJan-Uwe Rohde Dr., Jan-Uwe Rohde Dr. Department of Chemistry, University of Minnesota (USA)Search for more papers by this authorLawrence Que Jr. Prof., Lawrence Que Jr. Prof. Department of Chemistry, University of Minnesota (USA)Search for more papers by this authorStephen P. Cramer Prof., Stephen P. Cramer Prof. Department of Applied Science, University of California, Davis Physical Biosciences Division, Lawrence Berkeley National Laboratory (USA)Search for more papers by this authorEdward I. Solomon Prof., Edward I. Solomon Prof. Edward.Solomon@stanford.edu Department of Chemistry, Stanford University, Stanford, CA 94305-5080 (USA), Fax: (+1) 650-725-0259Search for more papers by this author First published: 05 November 2008 https://doi.org/10.1002/ange.200803740Citations: 6 † NRVS=nuclear vibrational resonance spectroscopy. Use of the Advanced Photon Source at Argonne National Laboratory was supported by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. Financial support of this research was provided by NIH Grants GM65440 (S.P.C), GM33162 (L.Q.), and GM40392 (E.I.S.) and NSF-Biophysics Program Grant MCB-0342807 (E.I.S). We would like to thank Jiyong Zhao, Wolfgang Sturhahn, and the staff at beamline 3-ID for assistance and discussions regarding NRVS. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Des Pudels Kern: Biomimetische FeIVO-Modellkomplexe (Fe grün, O rot, N blau, C schwarz) wurden Kernschwingungsresonanz-spektroskopisch charakterisiert. Systematische Trends im Bereich niedriger Energie stehen für Unterschiede in den äquatorialen und axialen Bindungen, die mit Reaktivitätsunterschieden in Beziehung stehen. Diese Trends wurden genutzt, um die Spektren vermuteter FeIVO-Intermediate in Nicht-Häm-Eisenenzymen vorherzusagen. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_200803740_sm_miscellaneous_information.pdf633.3 KB miscellaneous information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume120, Issue47November 10, 2008Pages 9211-9214 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation