Dual‐Cure Coatings: Spiroorthoesters as Volume‐Controlling Additives in Thiol–Ene Reactions
2019; Wiley; Volume: 304; Issue: 4 Linguagem: Inglês
10.1002/mame.201970009
ISSN1439-2054
AutoresPhilipp Marx, Angelo Romano, Roland A. Fischer, Ignazio Roppolo, Marco Sangermano, Frank Wiesbrock,
Tópico(s)Advanced Polymer Synthesis and Characterization
ResumoMacromolecular Materials and EngineeringVolume 304, Issue 4 1970009 Cover PictureFree Access Dual-Cure Coatings: Spiroorthoesters as Volume-Controlling Additives in Thiol–Ene Reactions Philipp Marx, Philipp MarxSearch for more papers by this authorAngelo Romano, Angelo RomanoSearch for more papers by this authorRoland Fischer, Roland FischerSearch for more papers by this authorIgnazio Roppolo, Ignazio RoppoloSearch for more papers by this authorMarco Sangermano, Marco SangermanoSearch for more papers by this authorFrank Wiesbrock, Frank WiesbrockSearch for more papers by this author Philipp Marx, Philipp MarxSearch for more papers by this authorAngelo Romano, Angelo RomanoSearch for more papers by this authorRoland Fischer, Roland FischerSearch for more papers by this authorIgnazio Roppolo, Ignazio RoppoloSearch for more papers by this authorMarco Sangermano, Marco SangermanoSearch for more papers by this authorFrank Wiesbrock, Frank WiesbrockSearch for more papers by this author First published: 03 April 2019 https://doi.org/10.1002/mame.201970009Citations: 1AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Front Cover: In article number 1800627 by Marco Sangermano, Frank Wiesbrock, and co-workers, bicyclic spiroorthoesters undergo volumetric expansion upon cationic (double) ring-opening polymerization. They can be used as additives in polymerizations to control the shrinkage that conventional polymerizations exhibit; if the spiroorthoesters bear olefinic structural motifs, they can be covalently attached into thiol–ene networks, while the shrinkage/expansion can be tailored. Citing Literature Volume304, Issue4April 20191970009 RelatedInformation
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