Aryl CbH Activation by CuII To Form an Organometallic ArylâCuIII Species: A Novel Twist on Copper Disproportionation This research was supported by MICYT of Spain through project PBQ2000-0548 and with the grant SGR-3102-UG-01 as well as the Distinction award from from CIRIT Generalitat de Catalunya (Spain). An FI doctoral grant from CIRIT to X.R. and financial support from the National Institutes of Health (USA; T.D.P.S. GM-50730; K.O.H. RR-01209) are also acknowledged. SSRL operations are …
2002; Wiley; Volume: 114; Issue: 16 Linguagem: Alemão
10.1002/1521-3757(20020816)114
ISSN1521-3757
AutoresXavi Ribas, Deanne A. Jackson, B. Donnadieu, José MahÃa, Teodor Parella, Raà ⁄ l Xifra, Britt Hedman, Keith O. Hodgson, Antoni Llobet, T. Daniel P. Stack,
Tópico(s)Cyclopropane Reaction Mechanisms
ResumoAus einfachen triazamakrocyclischen Liganden und Kupfer(II)-Salzen entstehen unter milden Bedingungen die Produkte einer intramolekularen Aryl-C-H-Aktivierung und Metall-Disproportionierung [Gl. (1)]. Die neuen metallorganischen CuIII-Komplexe sind unter protischen Bedingungen stabil.
Referência(s)