A Water‐Soluble Titanium Complex for the Selective Synthesis of Nanocrystalline Brookite, Rutile, and Anatase by a Hydrothermal Method
2006; Wiley; Volume: 118; Issue: 15 Linguagem: Inglês
10.1002/ange.200503565
ISSN1521-3757
AutoresKoji Tomita, Valery Petrykin, Makoto Kobayashi, Motoo Shiro, Masahiro Yoshimura, Masato Kakihana,
Tópico(s)Copper-based nanomaterials and applications
ResumoAngewandte ChemieVolume 118, Issue 15 p. 2438-2441 Zuschrift A Water-Soluble Titanium Complex for the Selective Synthesis of Nanocrystalline Brookite, Rutile, and Anatase by a Hydrothermal Method† Koji Tomita Dr., Koji Tomita Dr. Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 1,1 Katahira, 2-Chome, Aobaku, Sendai 980-8577, Japan, Fax: (+81) 22-217-5649Search for more papers by this authorValery Petrykin Dr., Valery Petrykin Dr. Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 1,1 Katahira, 2-Chome, Aobaku, Sendai 980-8577, Japan, Fax: (+81) 22-217-5649Search for more papers by this authorMakoto Kobayashi, Makoto Kobayashi Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 1,1 Katahira, 2-Chome, Aobaku, Sendai 980-8577, Japan, Fax: (+81) 22-217-5649Search for more papers by this authorMotoo Shiro Dr., Motoo Shiro Dr. X-ray Research Laboratory, Rigaku Corporation, 3-9-12 Matsubara-cho, Akishima-shi, Tokyo, JapanSearch for more papers by this authorMasahiro Yoshimura Prof. Dr., Masahiro Yoshimura Prof. Dr. Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226-8503, JapanSearch for more papers by this authorMasato Kakihana Prof. Dr., Masato Kakihana Prof. Dr. [email protected] Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 1,1 Katahira, 2-Chome, Aobaku, Sendai 980-8577, Japan, Fax: (+81) 22-217-5649Search for more papers by this author Koji Tomita Dr., Koji Tomita Dr. Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 1,1 Katahira, 2-Chome, Aobaku, Sendai 980-8577, Japan, Fax: (+81) 22-217-5649Search for more papers by this authorValery Petrykin Dr., Valery Petrykin Dr. Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 1,1 Katahira, 2-Chome, Aobaku, Sendai 980-8577, Japan, Fax: (+81) 22-217-5649Search for more papers by this authorMakoto Kobayashi, Makoto Kobayashi Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 1,1 Katahira, 2-Chome, Aobaku, Sendai 980-8577, Japan, Fax: (+81) 22-217-5649Search for more papers by this authorMotoo Shiro Dr., Motoo Shiro Dr. X-ray Research Laboratory, Rigaku Corporation, 3-9-12 Matsubara-cho, Akishima-shi, Tokyo, JapanSearch for more papers by this authorMasahiro Yoshimura Prof. Dr., Masahiro Yoshimura Prof. Dr. Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226-8503, JapanSearch for more papers by this authorMasato Kakihana Prof. Dr., Masato Kakihana Prof. Dr. [email protected] Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 1,1 Katahira, 2-Chome, Aobaku, Sendai 980-8577, Japan, Fax: (+81) 22-217-5649Search for more papers by this author First published: 24 March 2006 https://doi.org/10.1002/ange.200503565Citations: 21 † This work was financially supported by CREST/JST, the Nippon Sheet Glass Foundation for Materials Science, and the Engineering and Collaborative Research Project of the Materials and Structures Laboratory of the Tokyo Institute of Technology. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Ein Komplex als Muster: Einphasige Brookit-, Rutil- und Rutil-Anatas-Nanopartikel lassen sich aus dem neuen wasserlöslichen Titan(IV)-Komplex (NH4)6[Ti4(C2H2O3)4(C2H3O3)2(O2)4O2]⋅4 H2O herstellen. Offenbar ist die strukturelle Ähnlichkeit des Komplexanions mit der Brookit-Architektur entscheidend für die gerichtete Synthese von Brookit-Nanopulvern in reiner Form (siehe Schema). Supporting Information Supporting Information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2006/z503565_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1M. Kakihana, M. Tada, M. Shiro, V. Petrykin, M. Osada, Y. Nakamura, Inorg. Chem. 2001, 40, 891–894. 10.1021/ic001098l CASWeb of Science®Google Scholar 2M. Dakanali, E. T. Kefalas, C. P. Raptopoulou, A. Terzis, G. Voyiatzis, I. Kyrikou, T. Mavromoustakos, A. Salifoglou, Inorg. Chem. 2003, 42, 4632–4639. 10.1021/ic0343051 CASPubMedWeb of Science®Google Scholar 3Y. F. Deng, Z. H. Zhou, H. L. Wan, Inorg. Chem. 2004, 43, 6266–6273. 10.1021/ic0496018 CASPubMedWeb of Science®Google Scholar 4M. Kakihana, K. Tomita, V. Petrykin, M. Tada, S. Sasaki, Y. Nakamura, Inorg. 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Mater. 2002, 14, 2845–2846. 10.1021/cm011542y CASWeb of Science®Google Scholar 14Crystallographic data: diffractometer Rigaku RAXIS-RAPID; chemical formula: (NH4)6[Ti4(C2H2O3)4(C2H3O3)2(O2)4O2]⋅4 H2O; crystal color: yellow; habit: platelet; crystal dimensions: 0.28×0.17×0.03 mm3; monoclinic; space group: P21/n (no. 14); a=12.04(1), b=9.203(6), c=16.58(1) Å, β=102.04(3)°; V=1796(2) Å3, T=(180±1) °C, FW=978.12, Z=2, MoKα (λ=0.71075 Å; graphite-monochromated), ρcalc=1.808 g cm−3, μ=9.76 cm−1, total reflections=21 111, unique reflections=5180, Rint=0.029, Lorentz-polarization absorption correction (transmission factors: 0.825–0.971). The structure was solved by direct methods (SHELX97)[15] and expanded using Fourier techniques.[16] The non-hydrogen atoms were refined anisotropically. Hydrogen atoms were refined using a riding model. Refinement was carried out by full-matrix least-squares on F2. wR2=[∑(−)2]/∑w()2]1/2 and R1=∑||Fo|−|Fc||/∑|Fo|. R1=0.027, wR=0.073, goodness of fit 1.060. CCDC 282608 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif. Google Scholar 15G. M. Sheldrick, SHELX97—Programs for Crystal Structure Analysis, University of Göttingen, Germany, 1997. Google Scholar 16P. T. Beurskens, G. Admiraal, G. Beurskens, W. P. Bosman, R. de Gelder, R. Israel, J. M. M. Smits, The DIRDIF-99 program system, Technical Report of the Crystallography Laboratory, University of Nijimegen, Netherlands, 1999. Google Scholar 17I. D. Brown, D. Altermatt, Acta Crystallogr. Sect. B 1985, 41, 244–247. 10.1107/S0108768185002063 CASGoogle Scholar Citing Literature Volume118, Issue15April 3, 2006Pages 2438-2441 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. 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