Cross-metathesis reaction. Generation of highly functionalized olefins from unsaturated alcohols
2001; Elsevier BV; Volume: 634; Issue: 2 Linguagem: Inglês
10.1016/s0022-328x(01)01125-1
ISSN1872-8561
AutoresJanine Cossy, Samir BouzBouz, Amir H. Hoveyda,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoA cross-metathesis reaction was achieved between acid- and base-sensitive functionalized olefins and electron-deficient olefins or allylsilane by using the recyclable ruthenium catalyst V at room temperature. The cross-metathesis products are isolated in moderate to good yield. Ratios of E and Z cross-metathesis products depend upon substituents on the electron-deficient coupling partner.
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