Through-space hopping transport in an iodine-doped perylene-based metal–organic framework
2022; Royal Society of Chemistry; Volume: 7; Issue: 9 Linguagem: Inglês
10.1039/d2me00108j
ISSN2058-9689
AutoresGonçalo Valente, María Esteve-Rochina, Ana Paracana, Antonio Rodrı́guez-Diéguez, Duane Choquesillo‐Lazarte, Enrique Ortı́, Joaquín Calbo, Marina Ilkaeva, Luís Mafra, Miguel A. Hernández‐Rodríguez, João Rocha, H. Alves, Manuel Souto,
Tópico(s)Covalent Organic Framework Applications
ResumoWe report the electrical conductivity enhancement of a perylene-based MOF upon partial ligand oxidation. The conductivity enhancement is rationalised by quantum-chemical calculations, supporting a through-space hopping transport.
Referência(s)